Creation of Polymeric Organosilicon Layers on the Surface of Pipeline Steel for Inhibition of Stress Corrosion Cracking

The article deals with the study of stress corrosion cracking (SCC) of X70 steel using corrosion-mechanical testing that simulates the operating conditions of underground pipelines. The tests were carried out under cyclic four-point bending at stresses close to the yield point, in electrolytes with various hydrogen charging capacities. The following model environments were used: NS4 solution and citrate buffer (pH 5.5). Hydrogen charging was controlled by the addition of thiourea and by varying the potential. It was shown that microcracks initiated at corrosion defects (pits) and then emerged at the surface to form narrow cracks. The incubation period depends on the environment: under corrosive conditions it is approximately two times shorter than in the air. The size and nature of stress concentrators play a significant role: natural pits (~hundreds of μm) lead to crack formation within 24–28 days, whereas artificial holes (0.6–1 mm) lead to crack formation within 5–7 days. The effect of hydrogen was established: the acceleration is insignificant under moderate hydrogen charging, whereas the incubation period decreases sharply at high hydrogen charging. Critical hydrogen concentrations where its effect becomes significant were determined. Methods for inhibiting stress corrosion cracking by means of organosilicon films (vinyl- and aminosilanes, as well as their mixtures with inhibitors—benzotriazole and amines) were considered. The most effective composition is vinylsilane + benzotriazole: the time to crack initiation increases from 5 to 36 days, and the crack growth rate decreases.