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Article

Effect of Extensive Solar Ultra-Violet Irradiation on the Durability of High-Density Polyethylene- and Polypropylene-Based Wood–Plastic Composites

by
Mohammad N. Siddiqui
1,*,
Halim H. Redhwi
2,
Anthony L. Andrady
3,
Sarfaraz A. Furquan
4 and
Syed Hussain
5
1
Chemistry Department and IRC-Refining and Advanced Chemicals, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
2
Chemical Engineering Department and IRC-Refining and Advanced Chemicals, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
3
Department of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh, NC 27607, USA
4
Mechanical Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
5
Dhahran Techno-Valley, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
*
Author to whom correspondence should be addressed.
Polymers 2025, 17(1), 74; https://doi.org/10.3390/polym17010074
Submission received: 7 November 2024 / Revised: 25 December 2024 / Accepted: 27 December 2024 / Published: 30 December 2024
(This article belongs to the Section Polymer Composites and Nanocomposites)

Abstract

The natural and laboratory-accelerated weathering of wood–plastic composites (WPCs) based on high-density polyethylene (HDPE) and polypropylene (PP) plastics was investigated in this study. Injection molded samples of WPCs with different loadings of wood fiber ranging from 0 to 36 wt.% of wood were subjected to laboratory-accelerated weathering and natural weathering. The integrity of samples weathered to different extents was tested using a standard tensile test and surface hardness test to investigate the dependence of these properties on the duration of weathering exposure. Tensile data were used to identify the loading of wood fibers in either plastic matrix that afforded superior ultra-violet (UV) stability. Tensile measurements under uniaxial strain yielded average values of tensile strength (TS), low-extension modulus (E), and elongation at break (EB). Both natural weathering outdoors and accelerated weathering in the laboratory showed that the TS and EB decreased while the E increased with the duration of exposure for all samples tested. The change in the average TS of composites with the duration of exposure offers valuable insights. The correlation between the tensile and hardness data for the WPC samples was explored. After naturally weathering at two exposure sites, the hardness of the WPCs was found to decrease between 8% to 12.5%, depending on the composition and exposure location parameters. Furthermore, no marked difference in performance with increasing wood fiber beyond 18 wt.% was observed. WPCs can be a key parameter in environmental sustainability by being used in the building and packaging industries, which reduces carbon emissions and waste generation.
Keywords: wood–plastic composites; weatherability; HDPE; PP wood–plastic composites; weatherability; HDPE; PP

Share and Cite

MDPI and ACS Style

Siddiqui, M.N.; Redhwi, H.H.; Andrady, A.L.; Furquan, S.A.; Hussain, S. Effect of Extensive Solar Ultra-Violet Irradiation on the Durability of High-Density Polyethylene- and Polypropylene-Based Wood–Plastic Composites. Polymers 2025, 17, 74. https://doi.org/10.3390/polym17010074

AMA Style

Siddiqui MN, Redhwi HH, Andrady AL, Furquan SA, Hussain S. Effect of Extensive Solar Ultra-Violet Irradiation on the Durability of High-Density Polyethylene- and Polypropylene-Based Wood–Plastic Composites. Polymers. 2025; 17(1):74. https://doi.org/10.3390/polym17010074

Chicago/Turabian Style

Siddiqui, Mohammad N., Halim H. Redhwi, Anthony L. Andrady, Sarfaraz A. Furquan, and Syed Hussain. 2025. "Effect of Extensive Solar Ultra-Violet Irradiation on the Durability of High-Density Polyethylene- and Polypropylene-Based Wood–Plastic Composites" Polymers 17, no. 1: 74. https://doi.org/10.3390/polym17010074

APA Style

Siddiqui, M. N., Redhwi, H. H., Andrady, A. L., Furquan, S. A., & Hussain, S. (2025). Effect of Extensive Solar Ultra-Violet Irradiation on the Durability of High-Density Polyethylene- and Polypropylene-Based Wood–Plastic Composites. Polymers, 17(1), 74. https://doi.org/10.3390/polym17010074

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