Efficient Removal of Carcinogenic Azo Dyes from Water Using Iron(II) Clathrochelate Derived Metalorganic Copolymers Made from a Copper-Catalyzed [4 + 2] Cyclobenzannulation Reaction
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis
2.1.1. Synthesis of CM1 (Procedure A)
2.1.2. Synthesis of CM2
2.1.3. Synthesis of CM3
2.1.4. Synthesis of CBM
2.1.5. Synthesis of Copolymer CBP1 (Procedure B)
2.1.6. Synthesis of CBP2
2.1.7. Synthesis of CBP3
3. Results and Discussion
3.1. Synthesis
3.1.1. Synthesis of the Prototypical Monomer CBM
3.1.2. Synthesis of Copolymers CBP1-3
3.2. Methyl Red Adsorption Studies
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Entry | Copolymer a | Time in Days | CM b [M] | Yield (%) |
---|---|---|---|---|
1 | CBP1 | 2 | 2.5 × 10−2 | 48 |
2 | CBP1 | 2 | 1.25 × 10−2 | 65 |
3 | CBP1 | 2 | 6.0 × 10−3 | 83 |
4 | CBP2 | 2 | 6.0 × 10−3 | 95 |
5 | CBP3 | 2 | 6.0 × 10−3 | 90 |
Dye on CBP3 | Pseudo-First-Order Model | Pseudo-Second-Order Model | |||||||
---|---|---|---|---|---|---|---|---|---|
C0 (mg L−1) | qe,exp (mg g−1) | qe,cal (mg g−1) | k1 (min−1) | R2 | qe,cal (mg g−1) | k2 (min−1) | R2 | ||
MR | Linear | 500 | 76 | 79.35 | −0.00013 | 0.9821 | 179.21 | 1.83 × 10−5 | 0.6559 |
Non linear | 88.43 | 0.00709 | 0.9866 | 148 | 2.91 × 10−5 | 0.9851 |
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Baig, N.; Shetty, S.; Bargakshatriya, R.; Pramanik, S.K.; Alameddine, B. Efficient Removal of Carcinogenic Azo Dyes from Water Using Iron(II) Clathrochelate Derived Metalorganic Copolymers Made from a Copper-Catalyzed [4 + 2] Cyclobenzannulation Reaction. Polymers 2023, 15, 2948. https://doi.org/10.3390/polym15132948
Baig N, Shetty S, Bargakshatriya R, Pramanik SK, Alameddine B. Efficient Removal of Carcinogenic Azo Dyes from Water Using Iron(II) Clathrochelate Derived Metalorganic Copolymers Made from a Copper-Catalyzed [4 + 2] Cyclobenzannulation Reaction. Polymers. 2023; 15(13):2948. https://doi.org/10.3390/polym15132948
Chicago/Turabian StyleBaig, Noorullah, Suchetha Shetty, Rupa Bargakshatriya, Sumit Kumar Pramanik, and Bassam Alameddine. 2023. "Efficient Removal of Carcinogenic Azo Dyes from Water Using Iron(II) Clathrochelate Derived Metalorganic Copolymers Made from a Copper-Catalyzed [4 + 2] Cyclobenzannulation Reaction" Polymers 15, no. 13: 2948. https://doi.org/10.3390/polym15132948