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Janus Nanostructures from ABC/B Triblock Terpolymer Blends

Physical Chemistry and Center for Nanointegration Duisburg-Essen (CENIDE), University Duisburg-Essen, 47057 Duisburg, Germany
Institute of Physics, Johannes Gutenberg University Mainz, Staudingerweg 7, 55128 Mainz, Germany
Authors to whom correspondence should be addressed.
Polymers 2019, 11(7), 1107;
Received: 21 May 2019 / Revised: 16 June 2019 / Accepted: 28 June 2019 / Published: 30 June 2019
(This article belongs to the Special Issue Self-assembly of Block Copolymers)
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Lamella-forming ABC triblock terpolymers are convenient building blocks for the synthesis of soft Janus nanoparticles (JNPs) by crosslinking the B domain that is “sandwiched” between A and C lamellae. Despite thorough synthetic variation of the B fraction to control the geometry of the sandwiched microphase, so far only Janus spheres, cylinders, and sheets have been obtained. In this combined theoretical and experimental work, we show that the blending of polybutadiene homopolymer (hPB) into lamella morphologies of polystyrene-block-polybutadiene-block-polymethylmethacrylate (SBM) triblock terpolymers allows the continuous tuning of the polybutadiene (PB) microphase. We systematically vary the volume fraction of hPB in the system, and we find in both experiments and simulations morphological transitions from PB-cylinders to perforated PB-lamellae and further to continuous PB-lamellae. Our simulations show that the hPB is distributed homogeneously in the PB microdomains. Through crosslinking of the PB domain and redispersion in a common solvent for all blocks, we separate the bulk morphologies into Janus cylinders, perforated Janus sheets, and Janus sheets. These studies suggest that more complex Janus nanostructures could be generated from ABC triblock terpolymers than previously expected. View Full-Text
Keywords: block copolymers; bulk morphologies; DPD simulations; Janus nanostructures; polymer blending block copolymers; bulk morphologies; DPD simulations; Janus nanostructures; polymer blending

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Steinhaus, A.; Srivastva, D.; Nikoubashman, A.; Gröschel, A.H. Janus Nanostructures from ABC/B Triblock Terpolymer Blends. Polymers 2019, 11, 1107.

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