Amino-Functionalized Lead Phthalocyanine-Modified Benzoxazine Resin: Curing Kinetics, Thermal, and Mechanical Properties
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Methods
2.2.1. Preparation of P-ddm/APbPc Copolymers
2.2.2. Characterizations and Measurements
3. Results and Discussion
3.1. FTIR Analysis
3.2. Curing Behavior of P-ddm/APbPc Blends
3.3. Curing Kinetics
3.4. Impact Strength of Copolymers
3.5. Dynamic Mechanical Analysis
3.6. Thermogravimetric Analysis
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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APbPc (wt.%) | To (°C) | Tp (°C) | Tf (°C) | ΔH (J/g) |
---|---|---|---|---|
0 | 227.2 | 241.0 | 267.3 | 275.0 |
5 | 211.2 | 233.2 | 267.6 | 272.1 |
10 | 204.5 | 229.3 | 267.2 | 259.4 |
15 | 195.8 | 226.3 | 267.4 | 224.9 |
20 | 192.1 | 224.7 | 267.5 | 213.4 |
25 | 188.6 | 222.5 | 268.0 | 202.8 |
Heating Rate (°C/min) | ΔH0 (J/g) | ΔH01 (J/g) | ΔH02 (J/g) | ΔH01/ΔH0 | ΔH02/ΔH0 |
---|---|---|---|---|---|
2.5 | 235.42 | 147.44 | 87.98 | 0.63 | 0.37 |
5 | 236.66 | 150.04 | 86.62 | 0.63 | 0.37 |
10 | 237.83 | 153.90 | 83.93 | 0.65 | 0.35 |
15 | 238.27 | 155.69 | 82.58 | 0.65 | 0.35 |
20 | 238.72 | 152.83 | 85.89 | 0.64 | 0.36 |
Mean | 237.38 | 151.98 | 85.40 | 0.64 | 0.36 |
β (K/min) | αM1 | m1 | n1 | lnA1 | αM2 | m2 | n2 | lnA2 | ||
---|---|---|---|---|---|---|---|---|---|---|
2.5 | 0.105 | 0.531 | 0.170 | 1.453 | 36.323 | 0.223 | 0.525 | 0.350 | 1.220 | 26.209 |
5 | 0.092 | 0.538 | 0.152 | 1.504 | 36.318 | 0.219 | 0.533 | 0.344 | 1.227 | 26.262 |
10 | 0.086 | 0.524 | 0.143 | 1.524 | 36.312 | 0.231 | 0.521 | 0.361 | 1.201 | 26.250 |
15 | 0.077 | 0.517 | 0.132 | 1.571 | 36.323 | 0.233 | 0.541 | 0.359 | 1.181 | 26.256 |
20 | 0.074 | 0.528 | 0.125 | 1.560 | 36.282 | 0.240 | 0.541 | 0.371 | 1.175 | 26.161 |
Mean | 0.145 | 1.522 | 36.311 | 0.357 | 1.201 | 26.228 |
APbPc (wt.%) | G′ (MPa @ 50 °C) | Tg (°C) | ρ (mol/m3) |
---|---|---|---|
0 | 2675.9 | 217.6 | 1617.8 |
5 | 2991.0 | 212.8 | 2894.9 |
10 | 3241.2 | 206.6 | 4335.9 |
15 | 3303.7 | 202.4 | 4935.6 |
20 | 3413.1 | 196.6 | 5396.7 |
25 | 3678.9 | 193.0 | 6783.2 |
APbPc (wt.%) | T5% (°C) | T10% (°C) | Yc (%, at 800 °C) |
---|---|---|---|
0 | 320.6 | 357.8 | 41.6 |
5 | 319.6 | 356.8 | 44.6 |
10 | 315.5 | 355.7 | 45.5 |
15 | 310.3 | 350.6 | 45.8 |
20 | 303.1 | 346.4 | 46.3 |
25 | 290.7 | 340.2 | 46.8 |
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Zu, L.-w.; Gao, B.-c.; Pan, Z.-c.; Wang, J.; Dayo, A.Q.; Liu, W.-b. Amino-Functionalized Lead Phthalocyanine-Modified Benzoxazine Resin: Curing Kinetics, Thermal, and Mechanical Properties. Polymers 2019, 11, 1855. https://doi.org/10.3390/polym11111855
Zu L-w, Gao B-c, Pan Z-c, Wang J, Dayo AQ, Liu W-b. Amino-Functionalized Lead Phthalocyanine-Modified Benzoxazine Resin: Curing Kinetics, Thermal, and Mechanical Properties. Polymers. 2019; 11(11):1855. https://doi.org/10.3390/polym11111855
Chicago/Turabian StyleZu, Li-wu, Bao-chang Gao, Zhong-cheng Pan, Jun Wang, Abdul Qadeer Dayo, and Wen-bin Liu. 2019. "Amino-Functionalized Lead Phthalocyanine-Modified Benzoxazine Resin: Curing Kinetics, Thermal, and Mechanical Properties" Polymers 11, no. 11: 1855. https://doi.org/10.3390/polym11111855