Microwave-Assisted Classic Ullmann C–C Coupling Polymerization for Acceptor-Acceptor Homopolymers
Abstract
:1. Introduction
2. Results and Discussion
2.1. Ullmann Polymerization
2.2. Optical and Electrochemical Properties
2.3. DFT Calculation
2.4. Fabrication and Characterization of All-PSCs
3. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Entry a | Solvent | T (°C) | Time (h) | Heat | Yield (%) | Repeat Unit b |
---|---|---|---|---|---|---|
1 | DMSO | 80 | 12 | Oil Bath | 0 | No |
2 | Toluene | 80 | 12 | Oil Bath | 0 | No |
3 | DMF | 80 | 12 | Oil Bath | 0 | No |
4 | DMF | 150 | 12 | Oil Bath | 30 | 5 |
5 | DMF | 150 | 24 | Oil Bath | 32 | 6 |
6 | DMF | 150 | 5 | M. W. | 38 | 11 |
Material | λpeak a (nm) | λonset (eV) | Egb (eV) | LUMO (eV) | HOMO c (eV) |
---|---|---|---|---|---|
PPDI(H) | 532 | 638 | 1.94 | −4.00 | −5.94 |
PPDI(OD) | 545 | 667 | 1.87 | −4.05 | −5.92 |
PNDI(OD) | 531 | 575 | 2.16 | −3.84 | -6.00 |
Blend Film | PCE (%) | VOC (V) | JSC (mA·cm-2) | FF (%) |
---|---|---|---|---|
PTB7-Th:PPDI(H) | 2.87 ± 0.22 | 0.58 ± 0.01 | 11.24 ± 0.28 | 45.0 ± 0.5 |
PBDB-T:PPDI(H) | 1.95 ± 0.13 | 0.61 ± 0.01 | 7.88 ± 0.24 | 41.9 ± 0.4 |
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Li, Z.; Chen, Y.; Ye, P.; Jia, X.; Wu, X.; Wu, J.; Shi, Q.; Peng, A.; Huang, H. Microwave-Assisted Classic Ullmann C–C Coupling Polymerization for Acceptor-Acceptor Homopolymers. Polymers 2019, 11, 1741. https://doi.org/10.3390/polym11111741
Li Z, Chen Y, Ye P, Jia X, Wu X, Wu J, Shi Q, Peng A, Huang H. Microwave-Assisted Classic Ullmann C–C Coupling Polymerization for Acceptor-Acceptor Homopolymers. Polymers. 2019; 11(11):1741. https://doi.org/10.3390/polym11111741
Chicago/Turabian StyleLi, Zijie, Yusheng Chen, Pan Ye, Xiangli Jia, Xiaoxi Wu, Jianfei Wu, Qinqin Shi, Aidong Peng, and Hui Huang. 2019. "Microwave-Assisted Classic Ullmann C–C Coupling Polymerization for Acceptor-Acceptor Homopolymers" Polymers 11, no. 11: 1741. https://doi.org/10.3390/polym11111741