Preparation of the Yellow-Colored Aluminum Pigments with Double-Layer Structure Using a Crosslinked Copolymeric Dye
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of FGMAC
2.3. Preparation of PFMV
2.4. Preparation of Al@SiO2@PFMV
2.5. Characterization
3. Results and Discussion
3.1. Preparation and Characterization of PFMV
3.2. Preparation and Characterization of the Al@SiO2@PFMV
3.2.1. FTIR Analysis
3.2.2. XPS Analysis
3.2.3. Particle Size Analysis
3.2.4. Morphologies of the Aluminum Pigments
3.2.5. TG Analysis
3.3. Corrosion Resistance Tests
3.4. Chromatism Analysis
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample | Elemental Contents (PP, at%) | ||||
---|---|---|---|---|---|
Al | C | O | Si | N | |
raw Al | 49.78 | 25.4 | 24.82 | / | / |
Al@SiO2 | 3.93 | 12.25 | 42.6 | 41.22 | / |
Al@SiO2@PFMV | 3.74 | 40.02 | 24.83 | 24.38 | 7.03 |
Samples | Rq (nm) | Ra (nm) | Rmax (nm) |
---|---|---|---|
Al@SiO2 | 9.64 | 9.52 | 233.6 |
Al@SiO2@PFMV | 1.65 | 1.62 | 33.3 |
Samples | Aluminum Pigments | Al@SiO2 | Al@SiO2@PFMV | |
---|---|---|---|---|
15° | L* | 159.3 | 136.86 | 111.6 |
a* | −0.31 | −0.18 | −1.61 | |
b* | −2.68 | −0.53 | 14.04 | |
25° | L* | 109.68 | 109.82 | 94.04 |
a* | −1.03 | −0.73 | −2 | |
b* | −1.79 | −0.27 | 15.03 | |
45° | L* | 52.35 | 67.04 | 68.64 |
a* | −0.44 | −0.38 | −1.57 | |
b* | −1.19 | −0.27 | 14.56 | |
75° | L* | 31.73 | 41.27 | 49.5 |
a* | −0.52 | −0.7 | −1.34 | |
b* | −0.94 | 0.55 | 16.59 | |
110° | L* | 26.22 | 34.11 | 41.51 |
a* | −0.6 | −0.82 | −1.12 | |
b* | −1.1 | 0.82 | 18.5 |
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Wang, Z.; Nie, S.; Xia, R.; Lv, Y.; Cao, M.; Chen, M.; Dong, Q.; Su, L.; Chen, P.; Yang, B.; et al. Preparation of the Yellow-Colored Aluminum Pigments with Double-Layer Structure Using a Crosslinked Copolymeric Dye. Polymers 2018, 10, 1097. https://doi.org/10.3390/polym10101097
Wang Z, Nie S, Xia R, Lv Y, Cao M, Chen M, Dong Q, Su L, Chen P, Yang B, et al. Preparation of the Yellow-Colored Aluminum Pigments with Double-Layer Structure Using a Crosslinked Copolymeric Dye. Polymers. 2018; 10(10):1097. https://doi.org/10.3390/polym10101097
Chicago/Turabian StyleWang, Zhicheng, Shuping Nie, Ru Xia, Yang Lv, Ming Cao, Ming Chen, Qiannian Dong, Lifen Su, Peng Chen, Bin Yang, and et al. 2018. "Preparation of the Yellow-Colored Aluminum Pigments with Double-Layer Structure Using a Crosslinked Copolymeric Dye" Polymers 10, no. 10: 1097. https://doi.org/10.3390/polym10101097