Influence of the Crystal Surface on the Austenitic and Martensitic Phase Transition in Pure Iron
Physics Department and Research Center OPTIMAS, University Kaiserslautern, Erwin-Schrödinger-Straße, D-67663 Kaiserslautern, Germany
Author to whom correspondence should be addressed.
Received: 22 November 2018 / Revised: 11 December 2018 / Accepted: 12 December 2018 / Published: 14 December 2018
Using classical molecular dynamics simulations, we studied the influence that free surfaces exert on the austenitic and martensitic phase transition in iron. For several single-indexed surfaces—such as
as well as
surfaces—appropriate pathways exist that allow for the transformation of the surface structure. These are the Bain, Mao, Pitsch, and Kurdjumov–Sachs pathways, respectively. Tilted surfaces follow the pathway of the neighboring single-indexed plane. The austenitic transformation temperature follows the dependence of the specific surface energy of the native bcc phase; here, the new phase nucleates at the surface. In contrast, the martensitic transformation temperature steadily decreases when tilting the surface from the (100)
to the (110)
orientation. This dependence is caused by the strong out-of-plane deformation that (110)
facets experience under the transformation; here, the new phase also nucleates in the bulk rather than at the surface.
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MDPI and ACS Style
Meiser, J.; Urbassek, H.M. Influence of the Crystal Surface on the Austenitic and Martensitic Phase Transition in Pure Iron. Crystals 2018, 8, 469.
Meiser J, Urbassek HM. Influence of the Crystal Surface on the Austenitic and Martensitic Phase Transition in Pure Iron. Crystals. 2018; 8(12):469.
Meiser, Jerome; Urbassek, Herbert M. 2018. "Influence of the Crystal Surface on the Austenitic and Martensitic Phase Transition in Pure Iron." Crystals 8, no. 12: 469.
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