High-Temperature Degradation and Microstructural Evolution of 310S Stainless Steel in Carburizing Furnace Service

This study investigates the degradation and failure mechanisms of AISI 310S stainless steel conveyor belt wires operating under cyclic conditions up to 900 °C in a continuous carburizing furnace. Microstructural evolution and mechanical responses after service exposure were evaluated using optical microscopy, scanning electron microscopy (SEM) equipped with energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and Vickers microhardness testing. Results indicate that initial exposure led to σ-phase nucleation and the formation of a protective Cr₂O₃-SiO₂ oxide scale. However, prolonged service led to scale degradation driven by Na-containing residues from pre-cleaning agents, which reacted to form Na₂SiO₃ and NaAlSiO₄ phases. This degradation accelerated the growth of non-protective iron oxides (Fe₂O₃, Fe₃O₄). Simultaneously, the σ-phase decomposed into massive, continuous M₂₃C₆ and M₇C₃ carbide networks along grain boundaries, inducing severe chromium sensitization. Consequently, the matrix embrittled significantly, with Vickers hardness increasing from 150 HV to 290–340 HV. Fracture analysis confirmed that brittle intergranular cracking initiated at these carbide networks, oxide inclusions, and matrix pores. Ultimately, the synergistic effects of oxide scale degradation, extensive carbide precipitation, and grain boundary depletion caused the premature catastrophic failure of the conveyor mesh under cyclic operational stress.