Natural Fluorite from Órgiva Deposit (Spain). A Study of Its Pozzolanic and Mechanical Properties
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Methods
2.2.1. Preparation of the Sample
2.2.2. Calcination Test
2.2.3. X-ray Diffraction Analysis (XRD)
2.2.4. Scanning Electron Microscopy (SEM)
2.2.5. Raman Spectroscopy (RS)
2.2.6. Chemical Pozzolanicity Test (CPT)
- −
- [OH−]: is the concentration in hydroxyl ions (mmol/L).
- −
- V3: is the volume of the hydrochloric acid solution (0.1 mol/L).
- −
- f2: is the factor of the hydrochloric acid solution (0.1 mol/L).
- −
- [CaO]: is the concentration in calcium oxide (mmol/L).
- −
- V4: is the volume of EDTA solution used in the titration.
- −
- f1: is the factor of the EDTA solution.
2.2.7. Chemical Quality Analysis (CQA)
2.2.8. Mechanical Strength Test (MST)
3. Results and Discussion
3.1. X-ray Diffraction (XRD)
3.2. Scanning Electron Microscopy (SEM)
3.3. Raman Spectroscopy (RS)
3.4. Pozzolanicity Test (CPT) at 8 and 15 Days
3.5. Chemical Quality Analysis (CQA)
3.6. Mechanical Strength Test (MST)
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Proportion (Ratios) | Temperature of Calcination (°C) | Blaine Particle Fineness (BPF) for NF and CF (cm2/g) | |||
---|---|---|---|---|---|---|
PC 1:NF 2 (%) | PC:CF 3 (%) | NS 4 (g) | DW 5 (g) | |||
PC/NF-01 PC/NF-02 PC/NF-03 PC/NF-04 PC/NF-05 PC/NF-06 | 90:10 75:25 60:40 90:10 75:25 60:40 | - | 1350 | 225 | - | 2000 |
5000 | ||||||
PC/CF-07 PC/CF-08 PC/CF-09 PC/CF-10 PC/CF-11 PC/CF-12 | - | 90:10 75:25 60:40 90:10 75:25 60:40 | 1350 | 225 | 900 | 2000 |
5000 |
Compounds | Samples | |
---|---|---|
Natural Fluorite (NF) (%) | Calcined Fluorite (CF) (%) | |
Total SiO2 | 53.28 | 56.70 |
Reactive SiO2 | 51.36 | 55.75 |
MgO | 0.02 | 0.06 |
Total CaO | 30.34 | 28.66 |
Reactive CaO | 28.58 | 28.40 |
Fe2O3 | 0.10 | 0.15 |
Al2O3 | 0.23 | 0.15 |
I.R. * | 3.85 | 2.84 |
SiO2/(CaO + MgO) | 1.86 | 1.99 |
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Martín, D.A.; Costafreda, J.L.; Estévez, E.; Presa, L.; Calvo, A.; Castedo, R.; Sanjuán, M.Á.; Parra, J.L.; Navarro, R. Natural Fluorite from Órgiva Deposit (Spain). A Study of Its Pozzolanic and Mechanical Properties. Crystals 2021, 11, 1367. https://doi.org/10.3390/cryst11111367
Martín DA, Costafreda JL, Estévez E, Presa L, Calvo A, Castedo R, Sanjuán MÁ, Parra JL, Navarro R. Natural Fluorite from Órgiva Deposit (Spain). A Study of Its Pozzolanic and Mechanical Properties. Crystals. 2021; 11(11):1367. https://doi.org/10.3390/cryst11111367
Chicago/Turabian StyleMartín, Domingo A., Jorge Luis Costafreda, Esteban Estévez, Leticia Presa, Alicia Calvo, Ricardo Castedo, Miguel Ángel Sanjuán, José Luis Parra, and Rafael Navarro. 2021. "Natural Fluorite from Órgiva Deposit (Spain). A Study of Its Pozzolanic and Mechanical Properties" Crystals 11, no. 11: 1367. https://doi.org/10.3390/cryst11111367