Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Materials
3.2. Catalyst Preparation and Characterization
3.3. Experimental Setup and Catalytic Reactions
3.4. Analytical Methods
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Catalyst | Fe Content (wt.%) | BET Surface Area (m2/g) |
---|---|---|
Mayenite | - | 11.7 |
1.5% Fe/mayenite | 1.72 | 11.5 |
2.0% Fe/mayenite | 2.30 | 11.2 |
Catalyst | T50 (°C) | T90 (°C) | Conversion Rate (mol g−1 s−1) |
---|---|---|---|
Mayenite | 410 | 550 | 5.58 × 10−6 |
1.5% Fe/mayenite | 375 | 460 | 7.14 × 10−6 |
2.0% Fe/mayenite | 300 | 460 | 1.05 × 10−5 |
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Cucciniello, R.; Intiso, A.; Siciliano, T.; Palomares, A.E.; Martínez-Triguero, J.; Cerrillo, J.L.; Proto, A.; Rossi, F. Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance. Catalysts 2019, 9, 747. https://doi.org/10.3390/catal9090747
Cucciniello R, Intiso A, Siciliano T, Palomares AE, Martínez-Triguero J, Cerrillo JL, Proto A, Rossi F. Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance. Catalysts. 2019; 9(9):747. https://doi.org/10.3390/catal9090747
Chicago/Turabian StyleCucciniello, Raffaele, Adriano Intiso, Tiziana Siciliano, Antonio Eduardo Palomares, Joaquín Martínez-Triguero, Jose Luis Cerrillo, Antonio Proto, and Federico Rossi. 2019. "Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance" Catalysts 9, no. 9: 747. https://doi.org/10.3390/catal9090747