Catalytic Conversion of Carbohydrates to Furanic Derivatives in the Presence of Choline Chloride
Abstract
:1. Introduction
2. Synthesis of Furanic Derivatives in the Presence of ChCl (LMM) and a Catalyst
2.1. Lewis Acids as Catalysts
2.2. Brønsted Acids as Catalysts
2.3. Heteropolyacids as Catalysts
3. Synthesis of Furanic Derivatives in the Presence of a DES Composed of ChCl and a Carboxylic Acid
4. Conclusions
Acknowledgments
Conflicts of Interest
References
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Catalysts | Yield to HMF (%) | |
---|---|---|
Fructose/ChCl | Glucose/ChCl | |
FeCl3 | 59 | 15 |
ZnCl2 | 8 | 6 |
CrCl2 | 40 | 45 |
CrCl3 | 60 | 31 |
AlCl3∙6H2O | - | 70 1 |
Brønsted Acids | |||||
---|---|---|---|---|---|
p-TsOH | p-TSA | CO2 | BHC | GO | |
Yield to HMF (%) | 59 | 91 | 74 | 84 | 76 |
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Jérôme, F.; De Oliveira Vigier, K. Catalytic Conversion of Carbohydrates to Furanic Derivatives in the Presence of Choline Chloride. Catalysts 2017, 7, 218. https://doi.org/10.3390/catal7070218
Jérôme F, De Oliveira Vigier K. Catalytic Conversion of Carbohydrates to Furanic Derivatives in the Presence of Choline Chloride. Catalysts. 2017; 7(7):218. https://doi.org/10.3390/catal7070218
Chicago/Turabian StyleJérôme, François, and Karine De Oliveira Vigier. 2017. "Catalytic Conversion of Carbohydrates to Furanic Derivatives in the Presence of Choline Chloride" Catalysts 7, no. 7: 218. https://doi.org/10.3390/catal7070218