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Catalysts 2017, 7(6), 168;

The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review

Department of Chemistry, Masaryk University, Kotlarska 2, CZ-61137 Brno, Czech Republic
CEITEC MU, Masaryk University, Kamenice 5, CZ-62500 Brno, Czech Republic
Department of Chemistry, University of Tennessee, Knoxville, TN 37996-1600, USA
Centre of Polymer Systems, Tomas Bata University in Zlin, Tr. T. Bati 5678, CZ-76001 Zlin, Czech Republic
Author to whom correspondence should be addressed.
Academic Editor: Damien P. Debecker
Received: 13 April 2017 / Revised: 17 May 2017 / Accepted: 18 May 2017 / Published: 25 May 2017
(This article belongs to the Special Issue Sol–Gel Chemistry: A Toolbox for Catalyst Preparation)
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This review is devoted to non-hydrolytic sol-gel chemistry. During the last 25 years, non-hydrolytic sol-gel (NHSG) techniques were found to be attractive and versatile methods for the preparation of oxide materials. Compared to conventional hydrolytic approaches, the NHSG route allows reaction control at the atomic scale resulting in homogeneous and well defined products. Due to these features and the ability to design specific materials, the products of NHSG reactions have been used in many fields of application. The aim of this review is to present an overview of NHSG research in recent years with an emphasis on the syntheses of mixed oxides, silicates and phosphates. The first part of the review highlights well known condensation reactions with some deeper insights into their mechanism and also presents novel condensation reactions established in NHSG chemistry in recent years. In the second section we discuss porosity control and novel compositions of selected materials. In the last part, the applications of NHSG derived materials as heterogeneous catalysts and supports, luminescent materials and electrode materials in Li-ion batteries are described. View Full-Text
Keywords: non-hydrolytic; sol-gel; non-aqueous; metal oxides; porosity non-hydrolytic; sol-gel; non-aqueous; metal oxides; porosity

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Styskalik, A.; Skoda, D.; Barnes, C.E.; Pinkas, J. The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review. Catalysts 2017, 7, 168.

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