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Materials 2016, 9(7), 574;

Physico-Chemical Alternatives in Lignocellulosic Materials in Relation to the Kind of Component for Fermenting Purposes

Green Engineering and Resources, Department of Chemistry and Process and Resource Engineering, University of Cantabria, Avda. Los Castros s/n, Santander 39005, Spain
Faculty of Biotechnical Systems Engineering, Politehnica University of Bucharest, 313 Splaiul Independentei, Sector 6, Bucuresti 060042, Romania
Department of Forest Products Technology, School of Chemistry, Aalto University, P.O. Box 16300, Aalto FI-00076, Finland
Author to whom correspondence should be addressed.
Academic Editor: Jalel Labidi
Received: 16 May 2016 / Revised: 4 July 2016 / Accepted: 8 July 2016 / Published: 15 July 2016
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The complete bioconversion of the carbohydrate fraction is of great importance for a lignocellulosic-based biorefinery. However, due to the structure of the lignocellulosic materials, and depending basically on the main parameters within the pretreatment steps, numerous byproducts are generated and they act as inhibitors in the fermentation operations. In this sense, the impact of inhibitory compounds derived from lignocellulosic materials is one of the major challenges for a sustainable biomass-to-biofuel and -bioproduct industry. In order to minimise the negative effects of these compounds, numerous methodologies have been tested including physical, chemical, and biological processes. The main physical and chemical treatments have been studied in this work in relation to the lignocellulosic material and the inhibitor in order to point out the best mechanisms for fermenting purposes. In addition, special attention has been made in the case of lignocellulosic hydrolysates obtained by chemical processes with SO2, due to the complex matrix of these materials and the increase in these methodologies in future biorefinery markets. Recommendations of different detoxification methods have been given. View Full-Text
Keywords: biorefinery; fermentation; detoxification; lignocellulosic materials; inhibitors; fractionation biorefinery; fermentation; detoxification; lignocellulosic materials; inhibitors; fractionation

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Coz, A.; Llano, T.; Cifrián, E.; Viguri, J.; Maican, E.; Sixta, H. Physico-Chemical Alternatives in Lignocellulosic Materials in Relation to the Kind of Component for Fermenting Purposes. Materials 2016, 9, 574.

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