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Materials 2016, 9(4), 246;

An Effective Electrodeposition Mode for Porous MnO2/Ni Foam Composite for Asymmetric Supercapacitors

Department of Chemical and Materials Engineering, National Kaohsiung University of Applied Sciences, Kaohsiung 80778, Taiwan
Department of Materials Engineering, Kun Shan University, Tainan 71070, Taiwan
Author to whom correspondence should be addressed.
Academic Editor: Douglas Ivey
Received: 16 February 2016 / Revised: 17 March 2016 / Accepted: 23 March 2016 / Published: 30 March 2016
(This article belongs to the Section Energy Materials)
Full-Text   |   PDF [3566 KB, uploaded 30 March 2016]   |  


Three kinds of MnO2/Ni foam composite electrode with hierarchical meso-macroporous structures were prepared using potentiodynamic (PD), potentiostatic (PS), and a combination of PS and PD(PS + PD) modes of electrodeposition. The electrodeposition mode markedly influenced the surface morphological, textural, and supercapacitive properties of the MnO2/Ni electrodes. The supercapacitive performance of the MnO2/Ni electrode obtained via PS + PD(PS + PD(MnO2/Ni)) was found to be superior to those of MnO2/Ni electrodes obtained via PD and PS, respectively. Moreover, an asymmetric supercapacitor device, activated carbon (AC)/PS + PD(MnO2/Ni), utilizing PS + PD(MnO2/Ni) as a positive electrode and AC as a negative electrode, was fabricated. The device exhibited an energy density of 7.7 Wh·kg−1 at a power density of 600 W·kg−1 and superior cycling stability, retaining 98% of its initial capacity after 10,000 cycles. The good supercapacitive performance and excellent stability of the AC/PS + PD(MnO2/Ni) device can be ascribed to its high surface area, hierarchical structure, and interconnected three-dimensional reticular configuration of the nickel metal support, which facilitates electrolyte ion intercalation and deintercalation at the electrode/electrolyte interface and mitigates volume change during repeated charge/discharge cycling. These results demonstrate the great potential of the combination of PS and PD modes for MnO2 electrodeposition for the development of high-performance electrodes for supercapacitors. View Full-Text
Keywords: electrodeposition; MnO2; Ni foam; asymmetric supercapacitor electrodeposition; MnO2; Ni foam; asymmetric supercapacitor

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Tsai, Y.-C.; Yang, W.-D.; Lee, K.-C.; Huang, C.-M. An Effective Electrodeposition Mode for Porous MnO2/Ni Foam Composite for Asymmetric Supercapacitors. Materials 2016, 9, 246.

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