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Correction published on 5 November 2009, see Materials 2009, 2(4), 1795.
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Progress to a Gallium-Arsenide Deep-Center Laser

Yale University, P.O. Box 208284, New Haven, CT 06520-8284, USA
Materials 2009, 2(4), 1599-1635;
Received: 14 September 2009 / Revised: 9 October 2009 / Accepted: 20 October 2009 / Published: 22 October 2009
(This article belongs to the Special Issue Luminescent Materials)
Although photoluminescence from gallium-arsenide (GaAs) deep-centers was first observed in the 1960s, semiconductor lasers have always utilized conduction-to-valence-band transitions. Here we review recent materials studies leading to the first GaAs deep-center laser. First, we summarize well-known properties: nature of deep-center complexes, Franck-Condon effect, hotoluminescence. Second, we describe our recent work: insensitivity of photoluminescence with heating, striking differences between electroluminescence and photoluminescence, correlation between transitions to deep-states and absence of bandgap-emission. Room-temperature stimulated-emission from GaAs deep-centers was observed at low electrical injection, and could be tuned from the bandgap to half-the-bandgap (900–1,600 nm) by changing the electrical injection. The first GaAs deep-center laser was demonstrated with electrical injection, and exhibited a threshold of less than 27 mA/cm2 in continuous-wave mode at room temperature at the important 1.54 μm fiber-optic wavelength. This small injection for laser action was explained by fast depopulation of the lower state of the optical transition (fast capture of free holes onto deep-centers), which maintains the population inversion. The evidence for laser action included: superlinear L-I curve, quasi-Fermi level separations satisfying Bernard-Duraffourg’s criterion, optical gains larger than known significant losses, clamping of the optical-emission from lossy modes unable to reach laser action, pinning of the population distribution during laser action. View Full-Text
Keywords: laser action; stimulated emission; electroluminescence; hotoluminescence; gallium-arsenide; deep-centers laser action; stimulated emission; electroluminescence; hotoluminescence; gallium-arsenide; deep-centers
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MDPI and ACS Style

Pan, J.L. Progress to a Gallium-Arsenide Deep-Center Laser. Materials 2009, 2, 1599-1635.

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