Corrosion Behavior of Ultra-High-Strength Hot-Press-Formed B-Pillar Parts
Abstract
1. Introduction
2. Experimental Procedures
2.1. Specimen Preparation
2.2. Microstructural and Coating Characterization
2.3. Cyclic Corrosion Immersion Test
2.4. Potentiodynamic Polarization Test
3. Results and Discussion
3.1. Microstructural Characteristics and Coating Crack Morphology
3.2. Corrosion Behavior During the Cyclic Corrosion Immersion Testing
3.3. Potentiodynamic Polarization Behavior
4. Conclusions
- The Al–Si coating exhibited a multilayered structure consisting of alternating Al- and Fe-rich layers, and the crack morphology was strongly dependent on the forming-induced stress state. Tensile deformation in the (Outer)LR region resulted in wide macrocracks, whereas compressive deformation in the (Inner)SR region resulted in the formation of narrow microcracks.
- Cyclic corrosion immersion tests revealed that the corrosion preferentially propagated along the coating cracks and was more severe on the inner surfaces than on the outer surfaces. The enhanced corrosion on the inner surface was attributed to crevice corrosion occurring within narrow microcracks, where chloride ion accumulation and local acidification accelerated corrosion, whereas wider macrocracks on the outer surface mitigated aggressive crevice conditions owing to enhanced electrolyte exchange.
- Potentiodynamic polarization tests showed similar corrosion rates for all regions; however, the (Outer)LR region exhibited a relatively noble corrosion potential, owing to oxide film formation on the locally exposed substrate areas and the suppression of crevice-corrosion-prone environments.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
- Yi, L.; Yu, G.; Tang, Z.; Li, X.; Gu, Z. Investigation of the hot stamping–in-die quenching composite forming process of 5083 aluminum alloy skin. Materials 2023, 16, 2742. [Google Scholar] [CrossRef]
- Gupta, M.K.; Singhal, V. Review on materials for making lightweight vehicles. Mater. Today Proc. 2022, 56, 868–872. [Google Scholar] [CrossRef]
- Mori, K.; Bariani, P.F.; Behrens, B.-A.; Brosius, A.; Bruschi, S.; Maeno, T.; Merklein, M.; Yanagimoto, J. Hot stamping of ultra-high strength steel parts. CIRP Ann. 2017, 66, 755–777. [Google Scholar] [CrossRef]
- Rosenthal, S.; Maaß, F.; Kamaliev, M.; Hahn, M.; Gies, S.; Tekkaya, A.E. Lightweight in automotive components by forming technology. Automot. Innov. 2020, 3, 195–209. [Google Scholar] [CrossRef]
- Essienubong, A.; Ikechukwu, I.O.; Satope, P. Design optimization of a B-pillar for crashworthiness of vehicle side impact. J. Mech. Eng. Sci. 2017, 11, 2693–2710. [Google Scholar] [CrossRef]
- Harrison, N.R.; Luckey, S.G. Hot stamping of a B-pillar outer from high strength aluminum sheet AA7075. SAE Int. J. Mater. Manuf. 2014, 7, 567–573. [Google Scholar] [CrossRef]
- Kim, Y.; Kang, M.-C. Mechanical and microstructural characteristics of 1.5 GPa-grade boron steel by high-frequency induction of eddy currents. Preprints 2023, 2023091736. [Google Scholar] [CrossRef]
- Merklein, M.; Lechler, J. Investigation of the thermo-mechanical properties of hot stamping steels. J. Mater. Process. Technol. 2006, 177, 452–455. [Google Scholar] [CrossRef]
- Naderi, M.; Ketabchi, M.; Abbasi, M.; Bleck, W. Analysis of microstructure and mechanical properties of different high strength carbon steels after hot stamping. J. Mater. Process. Technol. 2011, 211, 1117–1125. [Google Scholar] [CrossRef]
- Karbasian, H.; Tekkaya, A.E. A review on hot stamping. J. Mater. Process. Technol. 2010, 210, 2103–2118. [Google Scholar] [CrossRef]
- Wróbel, I.; Skowronek, A.; Grajcar, A. A review on hot stamping of advanced high-strength steels: Technological–metallurgical aspects and numerical simulation. Symmetry 2022, 14, 969. [Google Scholar] [CrossRef]
- Ikpe, A.E.; Orhorhoro, E.K.; Gobir, A. Design and reinforcement of a B-pillar for occupants safety in conventional vehicle applications. Int. J. Math. Eng. Manag. Sci. 2017, 2, 37. [Google Scholar] [CrossRef]
- Nomura, N.; Abe, M.; Yoshida, K.; Mori, K. Development of hot stamping technology for high-performance automotive parts. Nippon Steel Tech. Rep. 2019, 122, 21–27. [Google Scholar]
- Bok, H.-H.; Lee, M.-G.; Pavlina, E.J.; Barlat, F.; Kim, H.-D. Comparative study of the prediction of microstructure and mechanical properties for a hot-stamped B-pillar reinforcing part. Int. J. Mech. Sci. 2011, 53, 744–752. [Google Scholar] [CrossRef]
- Windmann, M.; Röttger, A.; Theisen, W. Phase formation at the interface between a boron alloyed steel substrate and an Al-rich coating. Surf. Coat. Technol. 2013, 226, 130–139. [Google Scholar] [CrossRef]
- Klassen, C.M.; Smith, R.D.L.; Daun, K.J. Characterizing the AlSi coating on 22MnB5 steel using Raman spectroscopy. Mater. Charact. 2022, 189, 112002. [Google Scholar] [CrossRef]
- Dosdat, L.; Petitjean, J.; Vietoris, T.; Clauzeau, O. Corrosion resistance of different metallic coatings on press-hardened steels for automotive applications. Steel Res. Int. 2011, 82, 726–733. [Google Scholar] [CrossRef]
- Başer, T.A.; Bilir, O.G.; Onaylı, A.; Bayram, A.; Barutçuoğlu, B.; Uzunboy, M.; Erişir, E. Decarburization effects on high-cycle fatigue of uncoated press-hardened steels. Mater. Test. 2023, 65, 1322–1335. [Google Scholar] [CrossRef]
- Gui, Z.-X.; Wang, K.; Zhang, Y.-S.; Zhu, B. Cracking and interfacial debonding of the Al–Si coating in hot stamping of pre-coated boron steel. Appl. Surf. Sci. 2014, 316, 595–603. [Google Scholar] [CrossRef]
- Wang, K.; Jin, Y.; Zhu, B.; Zhang, Y. Investigation on cracking characteristics of Al–Si coating on hot stamping boron steel parts based on surface strain analysis. Surf. Coat. Technol. 2017, 309, 282–294. [Google Scholar] [CrossRef]
- Chen, L.; Chen, W.; Cao, M.; Li, X. Performance comparison of Zn-based and Al–Si-based coating on boron steel in hot stamping. Materials 2021, 14, 7043. [Google Scholar] [CrossRef] [PubMed]
- Macháčková, N.; Rudomilova, D.; Prošek, T.; Sturel, T.; Brossard, M. Corrosion mechanism of press-hardened steel with aluminum–silicon coating in controlled atmospheric conditions. Metals 2025, 15, 97. [Google Scholar] [CrossRef]
- Allély, C.; Dosdat, L.; Clauzeau, O.; Ogle, K.; Volovitch, P. Anticorrosion mechanisms of aluminized steel for hot stamping. Surf. Coat. Technol. 2014, 238, 188–196. [Google Scholar] [CrossRef]
- Kim, S.O.; Yang, W.S.; Kim, S.J. Effects of the combined addition of Zn and Mg on corrosion behaviors of electropainted AlSi-based metallic coatings used for hot-stamping steel sheets. Materials 2020, 13, 3379. [Google Scholar] [CrossRef]
- Couto, C.P.; Andreatta, F.; Lanzutti, A.; Costa, I.; Panossian, Z.; De Graeve, I.; Terryn, H.; Rossi, J.L.; Revilla, R.I. Depth profiling approach to evaluate the influence of hot stamping on the local electrochemical behaviour and galvanic series of hot-dip Al–Si coating on 22MnB5 steel. Corros. Sci. 2021, 185, 109435. [Google Scholar] [CrossRef]
- Wang, Y.L.; Zhu, B.; Zhang, Y.S. New research progresses on hot stamping technology of high-performance sheet metal. In Advanced High Strength Steel and Press Hardening; World Scientific: Singapore, 2017. [Google Scholar] [CrossRef]
- Cui, M.; Wang, Z.; Wang, L.; Huang, Y. Numerical simulation and multi-objective optimization of partition cooling in hot stamping of the automotive B-pillar based on RSM and NSGA-II. Metals 2020, 10, 1264. [Google Scholar] [CrossRef]
- Jin, F.X.; Shen, Z.; Bian, Y.; Zhong, Z.P. Finite element simulation of influence of hot stamping process parameters on properties of 22MnB5 martensitic steel for automobile B-pillar. Heat Treat. Met. 2019, 46, 221–228. [Google Scholar]
- Palmieri, M.E.; Galetta, F.R.; Tricarico, L. Study of tailored hot stamping process on advanced high-strength steels. J. Manuf. Mater. Process. 2022, 6, 11. [Google Scholar] [CrossRef]
- Couto, C.P.; Revilla, R.I.; Politano, R.; Costa, I.; Panossian, Z.; De Graeve, I.; Rossi, J.L.; Terryn, H. Influence of austenitisation temperatures during hot stamping on the local electrochemical behaviour of 22MnB5 steel coated with hot-dip Al–Si. Corros. Sci. 2021, 190, 109673. [Google Scholar] [CrossRef]
- Couto, C.P.; Revilla, R.I.; Colosio, M.A.; Costa, I.; Panossian, Z.; De Graeve, I.; Rossi, J.L.; Terryn, H. Electrochemical behaviour of 22MnB5 steel coated with hot-dip Al–Si before and after hot-stamping process investigated by scanning Kelvin probe microscopy. Corros. Sci. 2020, 174, 108811. [Google Scholar] [CrossRef]








| Top Flat | Small Radius | Large Radius | |
|---|---|---|---|
| Inner | (Inner)TF | (Inner)SR | - |
| Outer | (Outer)TF | - | (Outer)LR |
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Ahn, K.; Jin, J.; Oh, J.; Jang, H. Corrosion Behavior of Ultra-High-Strength Hot-Press-Formed B-Pillar Parts. Materials 2026, 19, 976. https://doi.org/10.3390/ma19050976
Ahn K, Jin J, Oh J, Jang H. Corrosion Behavior of Ultra-High-Strength Hot-Press-Formed B-Pillar Parts. Materials. 2026; 19(5):976. https://doi.org/10.3390/ma19050976
Chicago/Turabian StyleAhn, KyungBin, JuYeon Jin, JoungSeok Oh, and HeeJin Jang. 2026. "Corrosion Behavior of Ultra-High-Strength Hot-Press-Formed B-Pillar Parts" Materials 19, no. 5: 976. https://doi.org/10.3390/ma19050976
APA StyleAhn, K., Jin, J., Oh, J., & Jang, H. (2026). Corrosion Behavior of Ultra-High-Strength Hot-Press-Formed B-Pillar Parts. Materials, 19(5), 976. https://doi.org/10.3390/ma19050976

