Microstructure and Mechanical Properties of a Ti-Al-Mo-V-Cr-Sn-Zr Titanium Alloy via Double-Annealing Heat Treatment

Achieving a favorable synergy of strength, ductility, and toughness is a critical challenge for expanding the engineering applications of titanium alloys. In this work, a medium-strength and high-toughness novel Ti-Al-Mo-V-Cr-Sn-Zr (named Ti62F) titanium alloy in the form of a Φ400 mm bar was adopted to systematically investigate the regulation behavior of double annealing on its microstructure and mechanical properties, and quantitative correlations between microstructural parameters and macroscopic properties were established. Increasing the cooling rate during the first annealing stage (air cooling, force air cooling and water quenching) significantly refined the secondary α (α_s) phase and reduced the volume fraction and size of the primary α (α_p) phase, leading to an increase in the ultimate tensile strength of the alloy from 1077 MPa to 1229 MPa. However, the impact-absorbed energy decreased from 51.5 J to 23.3 J. When the second annealing temperature was varied within the range of 625–675 °C, the ultimate tensile strength fluctuated slightly and the impact toughness increased moderately. Equiaxed α_p phase and relatively thick α_s can induce multiple crack deflections, prolong the crack propagation path and enhance energy absorption. Dislocations are mainly piled up at α/β phase boundaries, triggering void nucleation and growth, which dominate the ductility and toughness levels. Tensile twinning acts only as an auxiliary deformation mechanism and contributes limitedly to toughness. After heat treatment under the optimized schedule of 880 °C/2 h/AC + 650 °C/4 h/AC, the Ti62F alloy exhibits a superior strength–toughness balance compared with conventional medium-strength titanium alloys such as TA15, TC4, and TC4-DT. The findings can provide a heat treatment basis for microstructural regulation of large-size Ti62F bars and their engineering applications in aerospace structural components.