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Article

Diffusion and Critical Hydrogen Content of Carbon Steels with Different Strengths and Microstructures

1
Chair of General and Analytical Chemistry, Montanuniversitaet Leoben, Franz Josef-Straße 18, 8700 Leoben, Austria
2
Voestalpine Grobblech GmbH, Voestalpine-Strasse 3, 4020 Linz, Austria
*
Author to whom correspondence should be addressed.
Materials 2026, 19(1), 15; https://doi.org/10.3390/ma19010015 (registering DOI)
Submission received: 5 November 2025 / Revised: 9 December 2025 / Accepted: 17 December 2025 / Published: 19 December 2025
(This article belongs to the Section Corrosion)

Abstract

Four thermomechanically rolled carbon steels with different strength levels and microstructures, namely S355M, X65M, S960M, and S1100M, were selected, and their critical hydrogen contents Hcrit were determined. Hcrit is the hydrogen content where brittle fracture of the steel can occur. The Hcrit values for the four carbon steels are 2.03 (S355M), 0.91 (X65M), 0.32 (S960M), and 0.53 ppm (S1100M). Bainitic carbon steel S1100M outperforms lower-strength tempered martensitic steel S960M in terms of resistance to hydrogen embrittlement. All other steels follow the trend that a higher strength of steel results in a lower resistance to hydrogen embrittlement. The root cause for the beneficial behavior of bainitic steels is discussed.
Keywords: hydrogen diffusion; critical hydrogen content; carbon steel hydrogen diffusion; critical hydrogen content; carbon steel

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MDPI and ACS Style

Zwittnig, D.; Eichinger, M.; Mülleder, M.; Schindler, C.; Egger, R.; Mori, G. Diffusion and Critical Hydrogen Content of Carbon Steels with Different Strengths and Microstructures. Materials 2026, 19, 15. https://doi.org/10.3390/ma19010015

AMA Style

Zwittnig D, Eichinger M, Mülleder M, Schindler C, Egger R, Mori G. Diffusion and Critical Hydrogen Content of Carbon Steels with Different Strengths and Microstructures. Materials. 2026; 19(1):15. https://doi.org/10.3390/ma19010015

Chicago/Turabian Style

Zwittnig, Dino, Matthias Eichinger, Martin Mülleder, Claudius Schindler, Rupert Egger, and Gregor Mori. 2026. "Diffusion and Critical Hydrogen Content of Carbon Steels with Different Strengths and Microstructures" Materials 19, no. 1: 15. https://doi.org/10.3390/ma19010015

APA Style

Zwittnig, D., Eichinger, M., Mülleder, M., Schindler, C., Egger, R., & Mori, G. (2026). Diffusion and Critical Hydrogen Content of Carbon Steels with Different Strengths and Microstructures. Materials, 19(1), 15. https://doi.org/10.3390/ma19010015

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