Sustainable Cold Mix Asphalt: A Comprehensive Review of Mechanical Innovations, Circular Economy Integration, Field Performance, and Decarbonization Pathways
Abstract
1. Introduction
- Material innovation: A chemo-rheological optimization of the binder-aggregate interface.
- Performance validation: An analysis of advanced characterization methods and a critical look at the methodological gaps in current testing standards.
- Comparative Sustainability metrics: A life-cycle assessment (LCA) of modern CMA compared to traditional HMA/WMA alternatives.
2. Global Utilization and Economic–Environmental Rationale
3. Material Composition and Chemo-Rheological Design
- Aggregates: Aggregates form the backbone of CMA and are carefully selected to achieve an optimal gradation, typically with a nominal maximum size below 12.5 mm. The particle size distribution generally follows established gradation frameworks, such as LB-10 or UPM-13, ensuring a dense, stable aggregate matrix. Incorporating 4–8% limestone aggregate (≤0.075 mm) into the mix will result in an increase in packing density to greater than 78%, which can result in better load transfer and improved rigidity. Angular crushed aggregate with a Los Angeles (LA) abrasion value less than 25% provides superior interlock characteristics and superior rut-resistant characteristics under traffic conditions [32].
- Binder: Binder is the binding agent that holds the aggregate together; binder is usually an emulsified asphalt (cationic CSS-1h) or cutback asphalt (MC-70) with a bitumen content between 60 and 70%. The binders are engineered to exhibit predictable failure behavior, enabling demulsification within 30 min at 25 °C for proper application and early strength development. Bio-based diluents are often incorporated to improve workability at ambient temperature by decreasing viscosity from 10–20 cP to 1–3 Pa·s at 25 °C, while providing a minimum flash point of 200 °C to ensure a safe, performant product [4,33].
- Additives: A range of polymeric and nano-scale modifiers are employed to strengthen the cohesion–adhesion balance of the mix [34]. Common examples include SBS elastomers (around 2% by weight) and nano-clay (0.5–1.5% by weight), both of which can boost Marshall stability from 0.5–1.5 kN in unmodified CMA to 4–12 kN in modified mixtures. Anti-stripping agents, such as hydrated lime (1–2% by weight), are also incorporated to improve moisture resistance, helping the mix retain a TSR of over 85% after 24 h of water immersion [35,36].
3.1. Emulsion Chemistry and Its Influence on CMA Performance
3.1.1. Emulsion Type and Electrical Charge

3.1.2. Breaking Mechanism and Curing Behavior
- Stage I-Flocculation: As water dilutes the surfactant, the zeta potential drops from stable ranges (+40–70 mV for cationic and −40–60 mV for anionic) to a critical level (~20–25 mV). Reduced electrostatic repulsion allows droplets to collide under Brownian motion, requiring <10 kT activation energy [41,42,43].
- Stage II-Coalescence: When the flocculated droplets come into contact with each other, a thin layer of water forms between them. The film will collapse when the capillary pressure is greater than 5 kPa. At that point, the residual zeta potential (approximately ±10–20 mV) will not be enough to prevent the droplets from merging more rapidly [41,42,43].
- Stage III-Curing: In the final stage of this process, the remaining water between the droplets will evaporate, and the binder will redistribute until the asphalt film has solidified. If there is too much humidity (greater than 90%), then the curing of the asphalt film may take two to three times as long because the retained moisture will delay the complete coalescence of the droplets [41,42,43].

3.1.3. Formulation and Performance-Enhancing Additives
- Polymers: Styrene-Butadiene-Styrene (SBS) and other polymers are frequently incorporated into the base bitumen before emulsification. When the polymer is mixed into the bitumen, the polymer creates a network in the binder, which increases the binder’s elastic properties, increases rutting resistance, and extends the binder’s fatigue life [29,41].
- Adhesion Promoters: After choosing the right charge for the emulsion, chemicals called anti-stripping agents are commonly used to increase the adhesion between the aggregate and binder and to improve water resistance [41].
3.2. Global Emulsion Standards and Innovations
- Nordic (Sweden):
- Western Europe:
- Southeast Asia:
- Graphene
- Microencapsulated bio-rejuvenators:
3.3. Cutback Asphalt: Composition, Classification, and Applications
- RC: Contains volatile solvents that evaporate quickly, allowing traffic to return rapidly. Ideal for patching and surface treatments.
- MC: Features a moderate evaporation rate, providing good workability and effectiveness for base courses and surface treatments [58].
- SC: Contains minimal volatile solvents, giving extended work time and suitability for prime coat applications and CMA treatments.
3.4. Aggregate and Water Composition
4. Production and Storage of CMA
4.1. Mixed-in-Place (MIP) CMA
4.2. Central-Plant Mixing (CPM) CMA
4.3. Construction Process of CMA
5. RAP in CMA: Rejuvenator-Driven Performance and Challenges
6. Mix Design Approaches for CMA
6.1. Overview of CMA Mix Design Philosophy
6.2. Laboratory-Based Mix Design
Key Factors Affecting Laboratory CMA Performance
| References | Conditioning Temperature | Time for Conditioning (Days) | Bitumen Type |
|---|---|---|---|
| [89] | 38 °C | 7, 28 | BM |
| Ambient | 1 | FM | |
| 38 °C | 7–14 | BM | |
| [85] | Ambient | 7 | FM |
| Ambient | 28 | FM | |
| 60 °C | 2 | FM | |
| [90] | 60 °C | 1, 3, and 7 | Both |
| [91] | 60 °C | 2 | BM |
| [92] | 40 °C | 18–21 | BM |
| [93] | 60 °C | 2 | Both |
| 20 °C | 101 | BM | |
| [94] | 38 °C, 40 °C, 60 °C | 1, 7, and 28 | BM |
| [81] | Ambient, 40 °C, 60 °C | 7–84 days (1–12 weeks) | CSS |
| [95] | 25 °C, 40 °C | 28 days | Foamed 50/70 bitumen |
6.3. Asphalt Institute Method of Mix Design
- 24 h in mold at 25 °C;
- 24 h in oven at 40 °C;
- 24 h stabilization in mold at 25 °C;
- 48 h water immersion (soaked stability evaluation).
- It does not specify acceptable porosity ranges.
- The definitions of fully cured and ultimate strength remain ambiguous.
- Moisture parameters used in volumetric analysis are inconsistent with modern standards.
6.4. Performance-Based Mix Design
- Low traffic (<3 MESA): ITS (dry/wet) and TSR;
- Medium traffic (3–6 MESA): ITS after moisture equilibration and soaking;
- High traffic (>6 MESA): triaxial testing for cohesion, friction angle, and moisture durability.
6.4.1. The Phenomenon of TSR Values Above 100%
6.4.2. Optimization of CMA Mix Design Using Response Surface Methodology (RSM)
7. Performance Evaluation of CMA
7.1. Laboratory Studies on the Performance of CMA
7.1.1. Effect of Aggregate and Gradation on the Performance of CMA
7.1.2. Effect of Additives on the Performance of CMA
7.1.3. Effect of Fillers on the Performance of CMA
7.1.4. Effect of Fiber Addition on the Performance of CMA
7.1.5. Effect of Compaction on the Performance of CMA
7.1.6. Effect of Curing on the Performance of CMA
- Curing time: Extending the curing period from 1 to 12 weeks raised the resilient modulus by 195% (0.85 → 2.51 GPa) and ITS by 144% (230 → 561 kPa) for the 4% BE mix.
- Moisture: Soaked curing reduced ITS by 14%, demonstrating moisture sensitivity.
- Emulsion dosage: Increased BE from 2% to 4% and cut rut depth from 13.6 to 9.0 mm and lengthened fatigue life by 49% [137].
7.2. Field Validation and Long-Term Performance of CMA
- Exceptional Durability under Heavy Traffic: On Scotland’s A90 trunk road, the Tayset CMA (70% RAP) exhibited no signs of distress after 10 years of service under extremely high traffic loads (>10 M ESA). Additionally, the stiffness stabilized at a very high level of 6 GPa within 6 months, demonstrating the long-term durability of the CMA, as well as significant carbon savings [139].
- Resilience in Extreme Climates: In a 15-year study in Sweden, it was demonstrated that CMA is a durable option, with the mix developing few cracks and no rutting over an extreme temperature range of −35 °C to 60 °C [140]. Conversely, field trials in China showed that, while AC-graded patches deteriorated rapidly in extreme cold winter conditions, open-graded LB patches did not develop defects after one year, demonstrating the importance of mix design for cold climates [141].
- Performance in High-Rainfall/High-Traffic Conditions: A CRM-E mix in Malaysia (100% RAP) displayed superior performance under extremely high rainfall and traffic (12,000 VPD/Lane). It produced higher stiffness levels than HMA (28–68%) and demonstrated excellent moisture resistance (TSR = 85–93%) and less than 2.5 mm of rutting after 12 months [142].
| Authors | Country | CMA Type | Climate and Traffic | Monitoring Duration | Summary of CMA Performance |
|---|---|---|---|---|---|
| Shenghua Wu, Cade Marty [14] | USA | 100% RAP cold mix (with rejuvenator) | Florida (subtropical); low-volume road | 22 months | The 100% RAP CMA exhibited only minor weathering and raveling after 3 years. No cracking or rutting observed. Same-day compaction recommended for improved density and reduced raveling. |
| J. Yi et al. [141] | China | Solvent-based liquid asphalt with limestone aggregates | Severe winter; medium traffic | 10 days–1 year | Field trials revealed that AC-graded cold mix patches failed within a month, whereas open-graded LB patches showed <30 mm deformation and remained intact after one year. The LB mix’s coarser skeleton and higher voids enabled faster curing and improved durability, making it more suitable for winter pothole repair. |
| Jin, Dongzhao et al. [143] | USA (Michigan) | Cold in-place recycling (CIR) | Cold, wet; low-volume road | 20-year modeled life | CIR improved cracking and fatigue resistance under freeze–thaw cycles. Predicted rutting and IRI increases remained minimal, validating CIR for the cold, wet region. |
| David Allain et al. [144] | USA | CIR | Subtropical (Medium) | N/A | CIR and full-depth reclamation enhanced the structural strength and durability of CMA pavements. |
| Charmot et al. [142] | Malaysia | CRM-E (100% RAP + 3.5% emulsion + 1.5% OPC; HMA overlay | High rainfall; warm; 12,000 vpd/lane | 12 months | CRM-E (100% RAP with emulsion and cement) performed exceptionally under high rainfall and traffic, showing 28–68% higher stiffness than HMA, strong moisture resistance (TSR 85–93%), minimal rutting (<2.5 mm), and no cracking after 12 months. A same-day HMA overlay further improved early strength without affecting long-term durability. |
| S. Kolo et al. [61] | Nigeria | DPWS-modified (Dissolved Polythene Waste Sachets) bitumen | Tropical/subtropical; urban traffic | 4 months (intensive field monitoring) | LB-graded CMA performed well in cold regions (<30 mm deformation/year), while AC-graded mixes failed early. In tropical climates, DPWS-modified CMA with recycled polythene showed higher strength and minimal settlement, emphasizing the value of CMA-specific standards and recycled materials. |
| Dennis Day et al. [139] | UK | Tayset CMA (70% RAP + 30% virgin aggregate) with C60B5 emulsion | Cold, damp; >10 million ESA | 10 years (2008–2018) | The Tayset CMA (70% RAP, 30% virgin aggregate, C60B5 emulsion) showed no distress after 10 years and 10 million ESAs on Scotland’s A90. Its stiffness stabilized at 6 GPa within six months, with strong rutting resistance and 43 t CO2 savings, confirming its long-term durability and environmental benefits. |
| Suda, J et al. [140] | Sweden | Cold bituminous emulsion mixture | Tropical/Sub-Tropical | 15 years | After 15 years (−35 °C to 60 °C range), CMA displayed few cracks, slow binder ageing, and no rutting. RAP sections outperformed conventional soft asphalt. CMA is validated as an eco-friendly, durable option. |
8. Environmental and Economic Impact of CMA
- SDG 11: CMA reduces reliance on virgin resources by incorporating RAP, WSA, and steel slag, thereby reducing landfill disposal and extending pavement life. For instance, using 100% RAP improves fatigue life by 49% and reduces permanent deformation. Steel slag provides a self-healing mechanism, enabling strength recovery of 74%, thus reducing future maintenance [150,151].
- SDG 9: Advanced materials stabilized by nano-silica, ternary PRBs, and 3D-printable geopolymers promote the mechanical properties of CMA as a basis for durable low-carbon infrastructure solutions.
- SDG 13: Innovations such as SBS binders with biodiesel blends, fly ashes, RHA, and microwave curing techniques reduce emissions of GHG in the process and enhance the curing and stiffness rates. That is, CKD and soda straw ash enhance the initial strength and reduce the need for heat techniques [148,150].


8.1. Innovations in CMA Formulation
8.1.1. Waste-Derived Fillers and Aggregates
8.1.2. Advanced Additives and Binders
8.1.3. Low-Energy and Accelerated Curing Techniques
8.1.4. Self-Healing and Durability Enhancements
8.1.5. Environmental Optimization
8.2. Sustainability Evaluation Through LCA of CMA Versus HMA
9. Performance Limitations and Field Implementation Challenges of CMA
9.1. Slow and Climate-Dependent Curing
9.2. Moisture Sensitivity and Adhesion
9.3. Long-Term Durability Uncertainties
9.4. Field Variability and Contractor Experience
- Moisture-induced stiffness scatter: Chongzheng Zhu [104] quantified the impact of stockpile moisture on 120 plant-produced CMA batches containing 35% RAP. A 1% increase in RAP free water elevated the effective binder content by 0.14% and reduced in situ air voids by 1.8%. Tensile adhesion decreased by 28% when the overnight relative humidity exceeded 85%. To mitigate this variability, contractors now enforce a 0–2% moisture limit and employ microwave sensors to adjust flux-oil dosage in real time [104].
- Temperature-driven viscosity window: A study reported by Ding et al. [7] recorded binder viscosity at 5 min intervals during 42 roadside trials under ambient temperatures ranging from 5 to 35 °C. Viscosity at 60 °C ranged from 1.1–2.0 Pa·s (CV = 18%), and the 1.6 Pa·s pot-life threshold was exceeded in 26% of loads, resulting in an average increase of 0.6 mm in Hamburg rutting depth. Consequently, a weather specification (substrate temperature ≥ 5 °C, relative humidity ≤ 85%) has been adopted to control field variability [7].
- Compaction variability at low temperature: Low temperature can result in a stiffer material (CMA), which makes the material less compactable; therefore, it has an uneven density and greater air voids. The results of these characteristics will lead to lower strength and less durability. It is necessary to adjust the appropriate mix design and optimize the compaction strategy to limit the variation that occurs with the temperature [83,133].
10. Conclusions and Future Direction
- Phase 1 (2025): Optimization of nano-additives (graphene oxide and nano-silica) to improve adhesion and moisture resistance.
- Phase 2 (2026–2027): AI-based forms predictive of the curing kinetics, the RAP–binder interaction, and the climate-dependent performance.
- Phase 3 (2028–2030): Utilization of IoT-enabled systems employing smart pavements and self-healing storms.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Nomenclature
| CMA | Cold Mix Asphalt |
| RAP | Reclaimed Asphalt Pavement |
| MS | Marshall Stability |
| IRAC | Initial Residual Asphalt Content |
| CSS | Cationic Slow-Setting (emulsion) |
| SF | Silica Fume |
| HMA | Hot Mix Asphalt |
| TSR | Tensile Strength Ratio |
| MQ | Marshall Quotient |
| IEC | Initial Emulsion Content |
| OPC | Ordinary Portland Cement |
| FA | Fly Ash |
| WMA | Warm Mix Asphalt |
| ITS | Indirect Tensile Strength |
| LCA | Life-Cycle Assessment |
| OTLC | Optimum Total Liquid Content |
| GGBS | Ground-Granulated Blast-furnace Slag |
| CKD | Cement Kiln Dust |
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| Category | AI MS-14 [65,72] | TG [96] | AASHTO PP 80-20 [99] | IRC: SP:100 [97,98] |
|---|---|---|---|---|
| Blend Classification | Well-graded or gap-graded aggregates | Traffic-dependent categories: BSM1 (>6 MESA), BSM2 (<6 MESA), BSM3 (<1 MESA). | Requires 100% crushing RAP to meet gradation targets; permits ≤15% virgin aggregates to correct deficiencies. | BM and SDBC mixes are specified. |
| IRAC/IEC Calculation | Empirical formulas with critical sieve sizes at 2.36 mm and 0.075 mm. | Not specified | Not specified | An empirical approach using 2.36 mm and 0.090 mm sieves as breakpoints. |
| Coating Requirements | ≥50% aggregate coating mandated. | Not specified | An aggregate coating of ≥90% is mandated, assessed visually during mixing. | Visual inspection for adequate coating (no quantitative threshold). |
| OTLC Determination | Derived from the moisture content yielding maximum dry density. | Optimum moisture content is established using modified AASHTO compaction. | Optimum water content determined at maximum dry density (modified Proctor). OTLC = Optimum water + foamed asphalt content. | Not specified |
| Variation in RAC | Maintains a constant OTLC | Not specified | Test ≥3 emulsion contents (e.g., 3.0%, 3.5%, 4.0%); select optimum via stability/voids. | Maintains the same OPWC, leading to a gradual increase in TLC. |
| Curing Process | Dry stability: 24 h mold (25 °C) → 24 h oven (40 °C) → 24 h mold (25 °C). Soaked: 48 h water immersion | Level 1: 72 h at 40 °C (unsealed). Levels 2–3: 26 h at 30 °C → sealed → 48 h at 40 °C | 72 h at 40 °C → 24 h at 25 °C (simulates 14-day field curing). | Air-dry loose mix (1–2 h) → oven-dry (40 °C, 2 h) → compact → 24 h mold (25 °C) → 72 h oven (40 °C). |
| Determination of ORAC | Maximizes soaked stability and dry density while meeting other criteria | Levels 1–2: indirect tensile strength (ITS) tests. Level 3: triaxial test results | Not Specified | It mainly focuses on maximum dry stability and density; soaked stability is not considered. |
| Moisture Damage | Stability values that have been retained are evaluated. | TSR values alongside moisture sensitivity tests are conducted | Stability values that have been retained are evaluated. | Analysis of retained ITS values. |
| Reference | Type of Emulsion/Asphalt | Blend Overview | Dosage | Curing | Key Results | Summary |
|---|---|---|---|---|---|---|
| Chongzheng Zhu [104] | CSS | RAP 84% + 12% virgin agg. + 4% mineral powder + 1.5% cement, FA, RH | 1.5% cement, FA, RH | 2 days @ 60 °C | ITS: 0.75–1.04 MPa; Stability: 1800–4200 passes/mm; TSR: 75–85% | FA maximized CRM tensile and low-temp performance; 0.75% FA + cement cut CO2 by ~50%. |
| Wenting Yang [33] | CSS | RAP 70% + limestone 30%; 4.4% added water | 4% emulsion; 0–2% cement | 2 days @ 60 °C, 3 days @ 20 °C + 2 days @ 60 °C | ITS: 0.74–0.94 MPa; AV: 10.3–11.7%; CSED: 2.03–2.77 kJ/m3 | Staged curing prioritizes cement hydration, producing a denser, stiffer matrix. |
| Li Yawen [49] | CSS | Aggregates + filler + cement (0–6%) | 8% emulsion + 0–6% cement | 28 days @ 23 °C, 55% RH | ITS: 540–1250 kPa; Stability: 6.8–13.1 kN; AV: 9–10% | 2% cement provides ≥80% of 28-day strength in 7 days; higher cement accelerates early strength. |
| Nassar et al. [105] | CE (C60B5) | Cold asphalt + OPC, FA, GGBS, Silica Fume | OPC: 8.8–43.9 g; additives 20–40% | - | ITSR: 80–105%; Stiffness: 282 MPa; AV: 8.5–9.8% | GGBS + SF reduces porosity and improves stiffness and durability. |
| Dulaimi [114] | CSS (C50B4) | 6% total filler: 4% GGBS + 2% CCR | 4% GGBS + 2% CCR | 3, 7, 56 days @ 20 °C | ITS: 1540–2510 MPa; AV: 8.9–9.2%; Rut: 3.2–3.5 mm; ITSR: 86–88% | 4% GGBS + 2% CCR outperforms limestone mixes, matches hot mix stiffness in 3 days. |
| Zhu Siyue [106] | SBS- Modified Emulsified Asphalt | CEAM + Cement + Fibers | 3% OPC, 0–0.2% fiber | 3–7 days @ 20 °C | ITS: 0.42–0.91 MPa; Flexural: 0.60–1.18 MPa; ITSM: 1050–2240 MPa; Rut: 2.5–4.8 mm; ITSR: 72–90% | 0.2% fiber + 3% OPC increases ITS, fatigue life, and reduces rut depth. |
| Chegeniza-deh [81] | CSS | 100% RAP + BE | 2–4% BE | 1–12 weeks @ 20 °C, soaked 24 h @ 25 °C | ITS: 230–561 kPa; RM: 771–2510 MPa; Rut: 9–13.6 mm; Fatigue: 102–153 k cycles | 4% CSS + 100% RAP optimizes stiffness, strength, fatigue, and rutting. |
| Rezaei [2] | Cutback/Emulsified/ Polymer-Modified | 9 cold mixes: DG + OG | Binder 2.4–6.7% | 24 h @ 25 °C, oven-cured 18 h @ 135 °C | MS: DG: 6.8–19 kN; OG: 3.4–10.1 kN; ITS: 370–1568 kPa; TSR: 0.64–1.06 | DG cold mixes with a low dust-to-binder ratio yield higher stability and the lowest rutting/moisture damage. |
| Mix ID | Cement (%) | Stage | Time (d) | Marshall Stability (kN) | ITS (kPa) | ITSM (MPa) |
|---|---|---|---|---|---|---|
| C0 | 0 | I | 0–3 | 2.0 | 250 | 520 (36%) |
| II | 3–14 | 4.8 | 600 | 1360 (95%) | ||
| III | 14–28 | 5.7 | 676 | 1435 | ||
| C2 | 2 | I | 0–3 | 5.0 | 370 | 3500 (52%) |
| II | 3–14 | 9.2 | 720 | 6300 (93%) | ||
| III | 14–28 | 10.5 | 807 | 6764 | ||
| C4 | 4 | I | 0–3 | 7.5 | 680 | 6300 (46%) |
| II | 3–14 | 15.2 | 1220 | 13,400 (97%) | ||
| III | 14–28 | 16.0 | 1331 | 13,805 | ||
| C6 | 6 | I | 0–3 | 13.3 | 730 | 8200 (46%) |
| II | 3–14 | 18.7 | 1420 | 16,100 (91%) | ||
| III | 14–28 | 21.0 | 1577 | 17,657 | ||
| HMA | — | — | — | — | — | 2705 |
| Material | Key Finding | Performance Gain | Sustainability Gain | Source |
|---|---|---|---|---|
| Wastewater sludge ash (WSA) | Replaces limestone filler; passes UK/EN leachability limits | Increase moisture resistance and durability | Eliminates calcination CO2 | [152] |
| RAP | 50% RAP > control stability; 100% RAP increased +49% fatigue life; decrease rut depth | Matches or exceeds virgin mix | Diverts waste; cuts virgin aggregate | [44,81] |
| Hybrid (50% RAP + 30% other recycled agg.) | Portland cement/bitumen emulsion binder achieves parity with HMA | Stable, durable mix | Reduces virgin content by ≥80% | [27,83,153] |
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Malik, M.D.; Chen, Y.; Mu, J.; Dong, R. Sustainable Cold Mix Asphalt: A Comprehensive Review of Mechanical Innovations, Circular Economy Integration, Field Performance, and Decarbonization Pathways. Materials 2025, 18, 5452. https://doi.org/10.3390/ma18235452
Malik MD, Chen Y, Mu J, Dong R. Sustainable Cold Mix Asphalt: A Comprehensive Review of Mechanical Innovations, Circular Economy Integration, Field Performance, and Decarbonization Pathways. Materials. 2025; 18(23):5452. https://doi.org/10.3390/ma18235452
Chicago/Turabian StyleMalik, Muhammad Danyal, Yongsheng Chen, Jian Mu, and Ruikun Dong. 2025. "Sustainable Cold Mix Asphalt: A Comprehensive Review of Mechanical Innovations, Circular Economy Integration, Field Performance, and Decarbonization Pathways" Materials 18, no. 23: 5452. https://doi.org/10.3390/ma18235452
APA StyleMalik, M. D., Chen, Y., Mu, J., & Dong, R. (2025). Sustainable Cold Mix Asphalt: A Comprehensive Review of Mechanical Innovations, Circular Economy Integration, Field Performance, and Decarbonization Pathways. Materials, 18(23), 5452. https://doi.org/10.3390/ma18235452

