Hereditary Behavior for Center Segregation and Inclusions in Q355 Steel Slabs with Ti and Nb Addition
Abstract
1. Introduction
2. Materials and Methods
3. Results
3.1. Hardness and Macrostructure of Casting Slab
3.2. Microstructure of Casting Slab
3.3. Central Segregation and Cavity of Casting Slab
3.4. Inclusions in Casting Slab
3.5. Thermodynamic Calculations
3.6. Thermal Simulation Test
4. Conclusions
- (1)
- The Mn steel exhibited well-developed dendritic structures, the most severe center segregation and cavities. The Nb steel showed the presence of thin film ferrite along prior grain boundaries surrounded by Widmanstätten ferrite, and the central segregation had not shown marked improvement with sole Nb addition. In contrast, the common addition of Ti and Nb in TiNb steel refined the grains and achieved a more uniform distribution of pearlite and cavities, leading to substantial improvements in central segregation.
- (2)
- In the thickness center of slab in Mn steel, the typical morphologies of MnS inclusions were dendritic. In TiNb steel, a large amount of irregularly shaped TiN/NbC were observed, whereas the typical morphologies of MnS inclusions were mainly rodlike or blocky. In Nb steel and TiNb steel, the deformable MnS inclusions usually wrapped TiN/NbC inclusions, reducing the detrimental effects of TiN/NbC inclusions. Thermodynamic calculations and the results from lattice mismatch theory indicated that TiN was likely to serve as a core for MnS formation.
- (3)
- The microstructure of double-pass compression thermal simulation steel plates exhibited a hereditary relationship with those of the continuously cast slabs. The same law was found in cast samples and thermal simulation samples, that is, the most serious center segregation occurred in Mn steel, followed by Nb steel, whereas TiNb steel without distinct segregation bands exhibited the most homogeneous microstructure and hardness distribution. Center segregation in casting slabs cannot be eliminated after double-pass compression, while the voids in the central segregation were gradually welded together as deformation increased. MnS inclusions were deformed from spherical or dendritic shapes to long strips during compression process.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | C | Si | Mn | P | S | Al | Nb | Ti | N |
---|---|---|---|---|---|---|---|---|---|
Mn steel | 0.16 | 0.17 | 1.25 | 0.020 | 0.011 | 0.004 | 0.003 | 0.001 | 0.0054 |
Nb steel | 0.18 | 0.19 | 0.56 | 0.024 | 0.006 | 0.005 | 0.009 | 0.002 | 0.0048 |
TiNb steel | 0.16 | 0.15 | 0.52 | 0.021 | 0.006 | 0.007 | 0.009 | 0.015 | 0.0062 |
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Tong, K.; Gao, Y.; Wang, H.; Huang, Z.; Wan, G.; Zhang, D.; Zuo, X. Hereditary Behavior for Center Segregation and Inclusions in Q355 Steel Slabs with Ti and Nb Addition. Materials 2025, 18, 4157. https://doi.org/10.3390/ma18174157
Tong K, Gao Y, Wang H, Huang Z, Wan G, Zhang D, Zuo X. Hereditary Behavior for Center Segregation and Inclusions in Q355 Steel Slabs with Ti and Nb Addition. Materials. 2025; 18(17):4157. https://doi.org/10.3390/ma18174157
Chicago/Turabian StyleTong, Keke, Ya Gao, Houxin Wang, Zhong Huang, Guoxi Wan, Dajiang Zhang, and Xiurong Zuo. 2025. "Hereditary Behavior for Center Segregation and Inclusions in Q355 Steel Slabs with Ti and Nb Addition" Materials 18, no. 17: 4157. https://doi.org/10.3390/ma18174157
APA StyleTong, K., Gao, Y., Wang, H., Huang, Z., Wan, G., Zhang, D., & Zuo, X. (2025). Hereditary Behavior for Center Segregation and Inclusions in Q355 Steel Slabs with Ti and Nb Addition. Materials, 18(17), 4157. https://doi.org/10.3390/ma18174157