Research on the Development of a Way to Modify Asphalt Mixtures with PET Recyclates
Abstract
:1. Introduction
2. Research Concept and Analyzing Methods
2.1. Materials
2.2. Methods
2.2.1. Tests Performed on Polymers
2.2.2. Tests Carried Out for Road Bitumens, Polymer-Modified Asphalt Mixes, and Polymer-Modified Asphalt Mixes with the Addition of Filler
3. Preparation of PET Recyclates
3.1. Characteristics of PET and PET Recyclates
3.1.1. Differential Scanning Calorimetry (DSC)
3.1.2. Thermogravimetric Analysis (TG)
3.1.3. Fourier Transform Infrared (FTIR) Spectroscopy
4. Properties of Road Construction Bitumen
4.1. The Influence of Temperature on the Penetration Value of Road Construction Bitumen
4.2. The Impact of Heating Road Construction Bitumen on the Softening Point Value Measured by the Ring-and-Ball Method
4.3. The Value of Elastic Recovery of Road Construction Bitumen Subjected to High Temperature
5. Preparation of Polymer-Modified Asphalt (PMA) Mixtures
5.1. Penetration Depth of Polymer-Modified Asphalt (PMA)
5.2. The Softening Point of Polymer-Modified Asphalt (PMA) by the Ring-and-Ball Method
5.3. The Elastic Recovery of Polymer-Modified Asphalt (PMA)
5.4. Study of the Structure of Polymer-Modified Asphalt (PMA)
6. Preparation of Polymer-Modified Asphalt (PMA) with the Addition of Mineral Filler
6.1. Characteristics of Polymer-Modified Asphalt Mixtures (PMA) with the Addition of Mineral Filler
6.1.1. Testing Resistance to the Effect of Negative Temperature—Frost Resistance of PMA Mixtures with Mineral Filler and Mineral-Modified Asphalt Mixtures from Tarnów
6.1.2. Examination of the Structure of PMA Mixtures with Mineral Filler and Mineral-Modified Asphalt Mixtures from Tarnów
6.1.3. Test of the Abrasion of Polymer-Modified Asphalt Mixtures with Mineral Filler and Mineral-Modified Asphalt Mixtures from Tarnów
7. Discussion
8. Conclusions
9. Future Perspectives
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Road Bitumens’ Type | Penetration at 25 °C (0.1 mm) | Softening Point (°C) | Application |
---|---|---|---|
50/70 | 50–70 | 46–54 | A component of mastic–grit mixtures (SMA) in wearing courses |
70/100 | 70–100 | 43–51 | A component of mastic–grit mixtures (SMA) in wearing courses |
100/150 | 100–150 | 39–47 | Production of asphalt emulsions |
Type of Road Construction Bitumen | Heating Temperature (°C) | d (mm) | RE (%) |
---|---|---|---|
50/70 | 150 | 25 | 13 |
240 | 10 | 5 | |
70/100 | 150 | 35 | 18 |
240 | 28 | 14 | |
100/150 | 150 | 23 | 12 |
240 | 33 | 17 |
Type of Road Construction Bitumen | Amount of Road-Construction Bitumen (wt%) | Amount of MRPET (wt%) | Amount of 10 M HCl (wt%) | Name of Sample |
---|---|---|---|---|
50/70 | 95.5 | 2 | 2.5 | 50/70/2RPET |
92.5 | 5 | 50/70/2RPET | ||
87.5 | 10 | 50/70/10RPET | ||
70/100 | 95.5 | 2 | 70/100/2RPET | |
92.5 | 5 | 70/100/5RPET | ||
87.5 | 10 | 70/100/10RPET | ||
100/150 | 95.5 | 2 | 100/150/2RPET | |
92.5 | 5 | 100/150/5RPET | ||
87.5 | 10 | 100/150/10RPET |
Type of Road Construction Bitumen | Sample | d (mm) | RE (%) |
---|---|---|---|
50/70 | 50/70 | 10 | 5 |
50/70/2MRPET | 21 | 11 | |
50/70/2MRPET | 48 | 24 | |
50/70/10MRPET | 29 | 15 | |
70/100 | 70/100 | 28 | 14 |
70/100/2MRPET | 11 | 6 | |
70/100/5MRPET | 31 | 16 | |
70/100/10MRPET | 30 | 15 | |
100/150 | 100/150 | 33 | 17 |
100/150/2MRPET | 30 | 15 | |
100/150/5MRPET | 35 | 18 | |
100/150/10MRPET | 35 | 18 |
(A) 50/70 | (B) 50/70/2MRPET | (C) 50/70/5MRPET | (D) 50/70/10MRPET |
---|---|---|---|
(A) 70/100 | (B) 70/100/2MRPET | (C) 70/100/5MRPET | (D) 70/100/10MRPET |
---|---|---|---|
(A) 100/150 | (B) 100/150/2MRPET | (C) 100/150/5MRPET | (D) 100/150/10MRPET |
---|---|---|---|
Type of Road Construction Bitumen | Amount of Road Construction Bitumen (wt%) | Amount of MRPET (wt%) | Amount of Mineral Filler (wt%) | Amount of 10 M HCl (wt%) | Name of Sample | |
---|---|---|---|---|---|---|
MB | PB | |||||
50/70 | 37.5 | 10 | 50 | - | 2.5 | 50/70/10MRPET/MB |
- | 50 | 50/70/10MRPET/WB | ||||
70/100 | 50 | - | 70/100/10MRPET/PB | |||
- | 50 | 70/100/10MRPET/WB | ||||
100/150 | 50 | - | 100/150/10MRPET/WB | |||
- | 50 | 100/150/10MRPET/WB |
Place of Taking a Sample of the Mineral-Modified Asphalt Mixtures | Name of Sample |
---|---|
Lwowska Street (50°00′52.5″ N 21°00′14.7″ E) | MMAL |
Moscickiego Street (50°00′50.7″ N 20°57′41.5″ E) | MMAL |
Kochanowskiego Street (50°00′21.5″ N 20°57′56.4″ E) | MMAL |
Mrozna Street (50°02′30.5″ N 20°58′05.1″ E) | MMAMR |
Frost Resistance | ||
---|---|---|
Sample | Before the Test | After the Test |
50/70/10MRPET/PB | ||
70/100/10MRPET/PB | ||
100/150/10MRPET/PB | ||
MMAL | ||
MMAM | ||
MMAK | ||
MMAMR |
Structure | ||
---|---|---|
Sample | Before the Test | After the Test |
50/70/10MRPET/PB | ||
70/100/10MRPET/PB | ||
100/150/10MRPET/PB | ||
MMAL | ||
MMAM | ||
MMAK | ||
MMAMR |
Sample | Abrasion (X) (mm3/m) |
---|---|
50/70/10MRPET/PB | 6.56 |
70/100/10MRPET/PB | 1.02 |
100/150/10MRPET/PB | 2.71 |
MMAL | 1.89 |
MMAM | 9.38 |
MMAK | 6.07 |
MMAK | 7.48 |
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Majka, T.M.; Ostrowski, K.A.; Piechaczek, M. Research on the Development of a Way to Modify Asphalt Mixtures with PET Recyclates. Materials 2023, 16, 6258. https://doi.org/10.3390/ma16186258
Majka TM, Ostrowski KA, Piechaczek M. Research on the Development of a Way to Modify Asphalt Mixtures with PET Recyclates. Materials. 2023; 16(18):6258. https://doi.org/10.3390/ma16186258
Chicago/Turabian StyleMajka, Tomasz M., Krzysztof Adam Ostrowski, and Marcin Piechaczek. 2023. "Research on the Development of a Way to Modify Asphalt Mixtures with PET Recyclates" Materials 16, no. 18: 6258. https://doi.org/10.3390/ma16186258