Basic Properties of MgAl-Mixed Oxides in CO2 Adsorption at High Temperature
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis of the Layered Double Hydroxides
2.2. Physico-Chemical Characterization Techniques
2.3. Basicity Measurement by SO2 Adsorption Calorimetry
2.4. CO2 Adsorption Tests
3. Results and Discussion
3.1. Characterization of the Hydrotalcite Precursors
3.2. Characterization of the Hydrotalcite-Derived Mixed Oxides
3.2.1. SO2 Adsorption Calorimetry
3.2.2. CO2 Adsorption Tests
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Al Source | Mg/Al Ratio | NaOH Amount (mL) |
---|---|---|---|
HTCL-1 | AlCl3.6H2O | 3.02 | 28 |
HTCL-3 | Al(C5H7O2)3 | 2.99 | 22 |
HTCL-5 | AlCl3.6H2O | 3.00 | 16 |
Sample | Weight Loss 25–200 °C (%) | Weight Loss 200–600 °C (%) | Total Weight Loss (%) | Comments | Ref. |
---|---|---|---|---|---|
HTCL-1 | 17.02 | 26.04 | 43.06 | - | This article |
HTCL-3 | 13.03 | 31.32 | 44.36 | - | This article |
HTCL-5 | 16.44 | 25.46 | 41.90 | - | This article |
LDH1 | 12.7 | 29.3 | 42.00 | Commercial MgAl LDH | [50] |
LDH2 | 15.2 | 26.7 | 41.90 | Commercial MgAl LDH | [50] |
LDH_amm | 15 | 38.83 | 53.83 | Coprecipitation with ammonia | [51] |
LDH_70 | 15 | 29 | 44.00 | Coprecipitation at low supersaturation, then pretreatment at 70 °C | [52] |
LDH_140 | 10 | 30 | 40.00 | Coprecipitation at low supersaturation, then pretreatment at 140 °C | [52] |
Mg/Al_LDH | 24 | 23 | 47.00 | Coprecipitation at low supersaturation | [53] |
Sample | Mg/Al Molar Ratio | Tpretreatment (°C) | Tadsorption (°C) | SSA (m2·g−1) | CO2 Adsorption Capacity (mmol·g−1) | Ref. |
---|---|---|---|---|---|---|
HTLC-1 CAL | 3 | 300 | 200 | 138 | 0.386 | This work |
HTLC-3 CAL | 3 | 300 | 200 | 180 | 0.527 | This work |
HTLC-5 CAL | 3 | 300 | 200 | 139 | 0.417 | This work |
HTLC_Low | 2 | 500 | 450 | 63 | 0.270 | [61] |
HTLC_High | 2 | 500 | 450 | 154 | 0.260 | [61] |
LDO200 | 3 | 400 | 200 | 167 | 0.486 | [62] |
Htlc-200 | 3 | 200 | 200 | 66 | 0.604 | [63] |
Htlc-400 | 3 | 400 | 200 | 184 | 0.896 | [63] |
Htlc | 3 | - | 300 | 74 | 0.5 | [64] |
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Chaillot, D.; Folliard, V.; Miehé-Brendlé, J.; Auroux, A.; Dzene, L.; Bennici, S. Basic Properties of MgAl-Mixed Oxides in CO2 Adsorption at High Temperature. Materials 2023, 16, 5698. https://doi.org/10.3390/ma16165698
Chaillot D, Folliard V, Miehé-Brendlé J, Auroux A, Dzene L, Bennici S. Basic Properties of MgAl-Mixed Oxides in CO2 Adsorption at High Temperature. Materials. 2023; 16(16):5698. https://doi.org/10.3390/ma16165698
Chicago/Turabian StyleChaillot, Dylan, Vincent Folliard, Jocelyne Miehé-Brendlé, Aline Auroux, Liva Dzene, and Simona Bennici. 2023. "Basic Properties of MgAl-Mixed Oxides in CO2 Adsorption at High Temperature" Materials 16, no. 16: 5698. https://doi.org/10.3390/ma16165698