Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Complex Compounds Synthesis
2.3. Elemental Analysis
2.4. IR Spectra
2.5. MALDI-TOF-MS Spectra
2.6. Oligomerization Process
3. Results and Discussion
- Stage I: formation of the catalytic system through the reaction between the complex compound (precatalyst) and the activator (MMAO-12);
- Stage II: matching the appropriate olefin to the active center;
- Stage III: incorporation of the olefin into the V-O bond by creating positive and negative partial charges.
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Complex Compound | Catalytic Activity [g · mmol−1· h−1] |
---|---|
[VOO(dipic)](2-phepyH) · H2O | 281.56 |
[VO(dipic)(dmbipy)] · 2 H2O | 522.07 |
[VO(oda)(H2O2)] | 1004.70 |
[VO(oda)(bipy)]· 2H2O | 499.53 |
[VO(ida)(H2O)]· H2O | 799.10 |
[VO(ida)(bipy)]·2 H2O | 811.13 |
[VO(ida)(phen)]· H2O | 608.97 |
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Drzeżdżon, J.; Pawlak, M.; Gawdzik, B.; Wypych, A.; Kramkowski, K.; Kowalczyk, P.; Jacewicz, D. Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization. Materials 2022, 15, 1379. https://doi.org/10.3390/ma15041379
Drzeżdżon J, Pawlak M, Gawdzik B, Wypych A, Kramkowski K, Kowalczyk P, Jacewicz D. Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization. Materials. 2022; 15(4):1379. https://doi.org/10.3390/ma15041379
Chicago/Turabian StyleDrzeżdżon, Joanna, Marta Pawlak, Barbara Gawdzik, Aleksandra Wypych, Karol Kramkowski, Paweł Kowalczyk, and Dagmara Jacewicz. 2022. "Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization" Materials 15, no. 4: 1379. https://doi.org/10.3390/ma15041379