Effect of P2O5 and Na2O on the Solubility of Molybdenum and Structural Features in Borosilicate Glass
Abstract
:1. Introduction
2. Experimental
2.1. Sample Preparation
2.2. Measurements
3. Results and Discussion
3.1. Glass Forming and Crystallization Analysis
3.2. Raman Spectra
3.3. 31P MAS NMR Spectroscopy
3.4. Thermal Stability and Aqueous Durability
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
References
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Samples | SiO2 | B2O3 | Na2O | P2O5 | MoO3 |
---|---|---|---|---|---|
NBS | 53.00 | 21.00 | 26.00 | ||
NBS-1Mo | 52.47 | 20.79 | 25.74 | 1 | |
NBS-2Mo | 51.94 | 20.58 | 25.48 | 2 | |
NBS-3Mo | 51.41 | 20.37 | 25.22 | 3 | |
NBS-4Mo | 50.88 | 20.16 | 24.96 | 4 | |
NBS-2P-4Mo | 49.82 | 19.74 | 24.44 | 2 | 4 |
NBS-4P-4Mo | 48.76 | 19.32 | 23.92 | 4 | 4 |
M19 | 53.76 | 19.32 | 18.92 | 4 | 4 |
M24 | 48.76 | 19.32 | 23.92 | 4 | 4 |
M29 | 43.76 | 19.32 | 28.92 | 4 | 4 |
M34 | 38.76 | 19.32 | 33.92 | 4 | 4 |
M34-1 | 37.07 | 18.48 | 32.45 | 8 | 4 |
Assignment | References | |
---|---|---|
Broad 750–775 | Six-membered borate rings containing BO4 tetrahedra | [41] |
Broad ~322 | Bending vibration of [MoO4]2− | [17] |
Broad ~900 | Symmetric stretching vibration of [MoO4]2− | [15] |
Broad 938–954 | vibration modes of Mo-O terminal bonds of Mo-O-P | [44] |
Sharp 338, 833, 842, 896 | Vibration modes of the [MoO4]2− of Na2MoO4 | [42] |
Sharp 292, 833, 872, 896, 920, 937 | Vibration modes of the [MoO4]2− of Na2MoO4 2H2O | [43] |
Samples | SiO2 | Na2O | Al2O3 | P2O5 | MoO3 |
---|---|---|---|---|---|
M19 | 66.63(64.92) | 23.45(21.79) | 0(2.72) | 4.96(4.64) | 4.96(5.91) |
M24 | 60.44(58.83) | 29.65(27.77) | 0(2.68) | 4.96(4.62) | 4.96(6.09) |
M29 | 54.24(51.86) | 35.85(34.54) | 0(2.76) | 4.96(4.60) | 4.96(6.21) |
M34 | 48.04(45.94) | 42.04(40.36) | 0(2.70) | 4.96(4.67) | 4.96(6.24) |
M34-1 | 45.47(43.32) | 39.84(36.15) | 0(5.01) | 9.81(9.23) | 4.91(6.27) |
Sample | Chemical Shift (ppm) | Phosphate Units | A (%) | Ref. |
---|---|---|---|---|
M19 | +5.5 | P0 | 27.40 | [18,27,31,33] |
+1.5 | P1 | 61.35 | ||
−4.4 | P21B/Al | 11.25 | ||
M24 | +5.1 | P0 | 28.38 | |
+1.5 | P1 | 61.99 | ||
−6.4 | P21B/Al | 9.63 | ||
M29 | +4.6 | P0 | 29.16 | |
+1.5 | P1 | 67.62 | ||
−6.9 | P21B/Al | 3.22 | ||
M34 | +4.5 | P0 | 24.95 | |
+1.3 | P1 | 75.05 |
Samples | M19 | M24 | M29 | M34 | M34-1 |
---|---|---|---|---|---|
Tg (°C) | 460 | 466 | 473 | 475 | 475 |
Tc (°C) | 590 | 578 | 581 | 573 | 579 |
Tc−Tg (°C) | 130 | 112 | 108 | 98 | 104 |
Na (LRNa)/ × 10−4 g·m−2·d−1 (28 d) | 6.04 | 6.59 | / | / | 6.65 |
Mo (LRMo)/ × 10−4 g·m−2·d−1 (28 d) | 1.80 | 1.29 | / | / | 3.73 |
P (LRP)/ × 10−4 g·m−2·d−1 (28 d) | 2.21 | 3.08 | / | / | 5.83 |
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Liu, H.; Zhu, Y.; Huo, J.; Cui, Z.; Zhang, X.; Jiang, Q.; Yang, D.; Meng, B. Effect of P2O5 and Na2O on the Solubility of Molybdenum and Structural Features in Borosilicate Glass. Materials 2022, 15, 5464. https://doi.org/10.3390/ma15155464
Liu H, Zhu Y, Huo J, Cui Z, Zhang X, Jiang Q, Yang D, Meng B. Effect of P2O5 and Na2O on the Solubility of Molybdenum and Structural Features in Borosilicate Glass. Materials. 2022; 15(15):5464. https://doi.org/10.3390/ma15155464
Chicago/Turabian StyleLiu, Hao, Yongchang Zhu, Jichuan Huo, Zhu Cui, Xingquan Zhang, Qin Jiang, Debo Yang, and Baojian Meng. 2022. "Effect of P2O5 and Na2O on the Solubility of Molybdenum and Structural Features in Borosilicate Glass" Materials 15, no. 15: 5464. https://doi.org/10.3390/ma15155464