Mid-Infrared Laser Generation of Zn1−xMnxSe and Zn1−xMgxSe (x ≈ 0.3) Single Crystals Co-Doped by Cr2+ and Fe2+ Ions—Comparison of Different Excitation Wavelengths
Abstract
:1. Introduction
2. Materials and Methods
2.1. Pumping Laser Systems
3. Results
3.1. Cr,Fe:ZnMnSe and Cr,Fe:ZnMgSe (x ≈ 0.3) Spectroscopic Properties
3.1.1. Absorption Spectra
3.1.2. Fluorescence Spectra
3.1.3. Fluorescence Decay Time and Energy Transfer Efficiency
3.2. Cr,Fe:ZnMnSe and Cr,Fe:ZnMgSe (x ≈ 0.3) Lasers’ Output Properties
3.2.1. Er:YLF Laser Excitation at 1.73 m
3.2.2. Er:YAG and Fe:ZnSe Laser Excitation at 2.94 and ∼4.05 m
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Laser; Operation Temperature | Central Osc. Wavelength (m) | Pulse Duration (FWHM) (ns) | Pulse Energy (mJ) | Repetition Rate (Hz) |
---|---|---|---|---|
(a) Q-switched Er:YLF; RT | 1.73 | 175 | ∼13 | 1 |
(b) Q-switched Er:YAG; RT | 2.94 | 160 | ∼14 | 2.5 |
(c) Fe:ZnSe; 78 K | ∼4.05 | 150 | ∼9 | 1 |
Crystal Sample | Cr Ions’ Absorption Band FWHM at 78/300 K | Cr Ions Max. Absorption Wavelength at 78/300 K | Fe Ions’ Absorption Band FWHM at 78/300 K | Fe Ions Max. Absorption Wavelength at 78/300 K |
---|---|---|---|---|
Cr,Fe:ZnMnSe (x ≈ 0.3) | 294/386 nm | 1774/1782 nm | 1060/1460 nm | 2930/2950–3200 nm |
Cr,Fe:ZnMgSe (x ≈ 0.3) | 370/416 nm | 1850/1870 nm | 1290/1540 nm | 3425/3425 nm |
Crystal Sample | Thickness (mm) | Absorption Coefficient at 1.73 m; 78/300 K | Absorption Coefficient at 2.94 m; 78/300 K | Absorption Coefficient at ∼4.05 m; 78/300 K |
---|---|---|---|---|
Cr,Fe:ZnMnSe (x ≈ 0.3) | 2.6 mm | 4.7/3.3 cm | 9.0/5.5 cm | 0.7/2.9 cm |
Cr,Fe:ZnMgSe (x ≈ 0.3) | 5.0 mm | 1.2/1.0 cm | 2.5/2.5 cm | 2.8/2.2 cm |
Temperature (K) | Crystal Sample, x ≈ 0.3 | Fluorescence Decay Time (1/e Level) (s) | Cr Lifetime (Measured at the Tail) (s) | Energy Transfer Efficiency According to Equation (1) (%) | Energy Transfer Efficiency According to Equation (2) (%) |
---|---|---|---|---|---|
78 K | Cr,Fe(Cr):ZnMnSe | 1.6 | 5.3 | 70 | 57 |
Cr,Fe(Cr):ZnMgSe | 1.7 | 5.0 | 66 | 53 | |
200 K | Cr,Fe(Cr):ZnMnSe | 1.3 | 5.3 | 75 | 62 |
Cr,Fe(Cr):ZnMgSe | 1.5 | 5.0 | 70 | 57 | |
300 K | Cr,Fe(Cr):ZnMnSe | 1.0 | 4.2 | 76 | 67 |
Cr,Fe(Cr):ZnMgSe | 1.0 | 4.0 | 75 | 65 |
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Říha, A.; Jelínková, H.; Doroshenko, M.E.; Jelínek, M.; Šulc, J.; Němec, M.; Vyhlídal, D.; Kovalenko, N.O. Mid-Infrared Laser Generation of Zn1−xMnxSe and Zn1−xMgxSe (x ≈ 0.3) Single Crystals Co-Doped by Cr2+ and Fe2+ Ions—Comparison of Different Excitation Wavelengths. Materials 2022, 15, 5277. https://doi.org/10.3390/ma15155277
Říha A, Jelínková H, Doroshenko ME, Jelínek M, Šulc J, Němec M, Vyhlídal D, Kovalenko NO. Mid-Infrared Laser Generation of Zn1−xMnxSe and Zn1−xMgxSe (x ≈ 0.3) Single Crystals Co-Doped by Cr2+ and Fe2+ Ions—Comparison of Different Excitation Wavelengths. Materials. 2022; 15(15):5277. https://doi.org/10.3390/ma15155277
Chicago/Turabian StyleŘíha, Adam, Helena Jelínková, Maxim E. Doroshenko, Michal Jelínek, Jan Šulc, Michal Němec, David Vyhlídal, and Nazar O. Kovalenko. 2022. "Mid-Infrared Laser Generation of Zn1−xMnxSe and Zn1−xMgxSe (x ≈ 0.3) Single Crystals Co-Doped by Cr2+ and Fe2+ Ions—Comparison of Different Excitation Wavelengths" Materials 15, no. 15: 5277. https://doi.org/10.3390/ma15155277