Design and Fabrication of New High Entropy Alloys for Evaluating Titanium Replacements in Additive Manufacturing
Abstract
:1. Introduction
2. Materials and Methods
2.1. Cost Analysis of Selected HEAs
- Cost of the metal powder (size <100 micrometer, usually atomized mill product)
- Cost of labor (metal mixture preparation efforts for selective laser melting)
- Cost of laser melting (equipment cost, hourly charges; laser power used in melting)
- Cost of post-deposition sample preparation steps (removal, polishing etc.)
2.2. Free Energy, Enthalpy, and Entropy Calculations
2.3. Calculations of Elastic Constants
2.4. Laser Components
2.5. Galvanometer Setup and Detail of Phidgets Hub for Laser-PBF Processing Control
2.6. Optimization of Parameters
2.7. Details about Closed Atmosphere Tests
2.8. Morphology, Elemental Characterizations, and Electron Backscatter Diffraction
2.9. Corrosion Behavior of HEAs
Accelerated Immersion Tests
2.10. Hardness Tests
2.11 Factorial Design of Experiments Testing
3. Results and Discussion
3.1. Elastic Properties
3.2. Analysis of Elastic Properties and Shortlisting of HEAs
3.3. Density Calculations for Short-Listed Alloys
3.4. X-ray Diffraction Tests
3.5. SEM/EBSD
3.6. Potentiodynamic Scans and EIS
3.7. Hardness Tests
3.8. Factorial Design of Experiments Laser Printing Test Matrix
3.9. Effect of Temperature (X-ray Diffraction Tests on Arc Melted Samples)
3.10. Reduced Elastic Constants for HEAs
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
Appendix A
Sr. no | High Entropy Alloy Composition | Sr. no | High Entropy Alloy Composition |
---|---|---|---|
1 | Al0.125CoCrCuFeMnNiTiV | 41 | Al1.2CrFe1.5MnNi0.5 |
2 | Al0.25CoCrCuFeMnNiTiV | 42 | CoCrCuFeMnNi |
3 | Al0.25CoCrCu0.75FeNi | 43 | CoCrCu0.5FeNi |
4 | Al0.3CoCrCuFeNi | 44 | CoCrCuFeNi |
5 | Al0.5CoCrCu0.5FeNi | 45 | Co0.25Cr0.25FeMn |
6 | Al0.5CoCrCuFeNi | 46 | CoCr0.4Fe8Mn5.4Ni5.2 |
7 | AlCoCrCu0.25FeNi | 47 | CoCr0.75FeMn0.75Ni |
8 | AlCo3.5CrCu0.5FeNi | 48 | CoCrFe0.5Mn0.5Ni1.5 |
9 | Al0.5CoCrCuFeNiTi0.2 | 49 | CoCrFeMnNi |
10 | Al0.25CoCrCuFeNiTiMnV | 50 | CoCr1.25FeMn0.25Ni |
11 | AlCoCrCu0.5Ni | 51 | CoCr1.3FeMnNi0.7 |
12 | Al0.02CoCrFeMnNi | 52 | Co1.4CrFeMnNi |
13 | Al0.03CoCrFeMnNi | 53 | Co1.5Cr0.5FeMn0.5Ni |
14 | Al0.04CoCrFeMnNi | 54 | CoCrFeMo0.3Ni |
15 | Al0.08CoCrFeMnNi | 55 | Co1.5CrFeMo0.1Ni1.5Ti0.5 |
16 | AlCo0.5Cr0.5Fe0.5MnNiV0.5 | 56 | CoCrFeNi |
17 | AlCo0.5Cr0.5Fe0.5MnNiV | 57 | Co1.5CrFeNi1.5Ti0.5 |
18 | Al0.3CoCrFeMo0.1Ni | 58 | CoCrMnNi |
19 | AlCoCrFeMo0.1Ni | 59 | CoCuFeMnNiSn0.03 |
20 | Al0.1CoCrFeNi | 60 | CoCuFeNi |
21 | Al0.25CoCrFeNi | 61 | CoCuFeNiTi |
22 | Al0.375CoCrFeNi | 62 | CoFeMnNi |
23 | Al0.4CoCrFeNi | 63 | CrCuFeMn2Ni2 |
24 | AlCoCrFeNi | 64 | Cr0.66FeMnNi |
25 | AlCoCrFeNiSi0.2 | 65 | CoFeNiSi0.25 |
26 | Al0.2Co1.5CrFeNi1.5Ti0.5 | 66 | CoMnNi |
27 | Al0.3CoCrFeNiTi0.1 | 67 | CrFeNi |
28 | AlCo3CuFeNi | – | – |
29 | Al0.25CoFeNi | – | – |
30 | AlCoFeNiTi | – | – |
31 | Al0.2CrCuFeNi | – | – |
32 | Al0.2CrCuFeNi2 | – | – |
33 | Al0.4CrCuFeNi | – | – |
34 | Al0.4CrCuFeNi2 | – | – |
35 | Al0.5CrCuFeNi | – | – |
36 | Al0.6CrCuFeNi2 | – | – |
37 | Al0.7CrCuFeNi | – | – |
38 | Al0.8CrCuFeNi2 | – | – |
39 | Al0.5CrFe1.5MnNi0.5 | – | – |
40 | Al0.8CrFe1.5MnNi0.5 | – | – |
Run | A | B | C | AB | AC | BC | ABC | Observation |
---|---|---|---|---|---|---|---|---|
1 | − | − | − | + | + | + | − | Y1 |
2 | + | − | − | − | − | + | + | Y2 |
3 | − | + | − | − | + | − | + | Y3 |
4 | + | + | − | + | − | − | + | Y4 |
5 | − | − | + | + | − | − | + | Y5 |
6 | + | − | + | − | + | − | − | Y6 |
7 | − | + | + | − | − | + | − | Y7 |
8 | + | + | + | + | + | + | + | Y8 |
High Entropy Alloy Composition | C11(GPa) | C12(GPa) | C44(GPa) | E(GPa) | B(GPa) | G(GPa) | B/G | ν | a0(Å) |
---|---|---|---|---|---|---|---|---|---|
AlCoCrFeNi | 214.82 | 135.38 | 167.59 | 284.31 | 169.74 | 116.442 | 1.45 | 0.2208 | 3.567 |
AlCoCrFeNiTi | 253.69 | 157.39 | 182.67 | 315.67 | 191.23 | 128.862 | 1.48 | 0.2248 | 3.781 |
AlCoCrFeNiMn | 248.71 | 153.61 | 179.14 | 309.60 | 186.77 | 126.504 | 1.47 | 0.2237 | 3.763 |
AlCrCuFeNi | 210.37 | 126.94 | 161.09 | 275.99 | 162.87 | 113.34 | 1.43 | 0.2175 | 3.579 |
CoCr1.3FeMnNi0.7 | 251.97 | 155.83 | 177.91 | 309.19 | 188.93 | 125.974 | 1.49 | 0.2272 | 3.774 |
AlCoCrFe | 168.94 | 84.96 | 137.93 | 237.53 | 128.96 | 99.554 | 1.29 | 0.1930 | 3.462 |
AlCrFeNi | 176.58 | 97.89 | 139.79 | 241.11 | 138.69 | 99.612 | 1.39 | 0.2102 | 3.458 |
AlCoFeNi | 173.71 | 92.68 | 138.95 | 240.37 | 136.74 | 99.576 | 1.37 | 0.2070 | 3.467 |
AlCoCr1.3FeNi1.3 | 262.82 | 151.73 | 172.98 | 308.79 | 187.38 | 126.01 | 1.49 | 0.225 | 4.091 |
AlCoCrFeNi1.3 | 237.83 | 134.97 | 162.67 | 291.22 | 181.23 | 118.17 | 1.53 | 0.232 | 3.994 |
AlCoCrFeNiTi0.9 | 257.99 | 144.58 | 164.14 | 296.51 | 178.77 | 121.17 | 1.47 | 0.223 | 4.203 |
AlCo0.8CrFeNiTi | 260.96 | 118.74 | 162.96 | 310.85 | 192.87 | 126.22 | 1.53 | 0.231 | 4.116 |
AlCo0.9CrFeNiMn0.9 | 242.66 | 142.68 | 168.93 | 294.03 | 169.85 | 121.35 | 1.4 | 0.211 | 4.118 |
AlCoFeNiZn0.85 | 181.83 | 102.75 | 145.89 | 247.01 | 134.98 | 103.35 | 1.31 | 0.195 | 3.962 |
AlCrFeNiMo0.1 | 185.58 | 112.89 | 143.96 | 246.27 | 146.69 | 100.91 | 1.45 | 0.220 | 3.467 |
AlCoCrFeMo0.1 | 188.71 | 117.68 | 151.79 | 255.55 | 148.74 | 105.28 | 1.41 | 0.214 | 3.463 |
AlCrCu0.8FeNi | 201.2 | 131.1 | 160.2 | 267.84 | 158.1 | 110.14 | 1.44 | 0.22 | 3.98 |
AlCrCuNiFe1.1 | 170.1 | 95.7 | 133.4 | 235.2 | 147.7 | 94.66 | 1.56 | 0.24 | 3.65 |
Alloy | Density (g/cm3) |
---|---|
AlCoCrFeNiMn | 6.79 |
CoCr1.3FeMnNi0.7 | 7.86 |
AlCoCrFeNi1.3 | 6.84 |
AlCoCr1.3FeNi1.3 | 6.86275 |
AlCoCrFeNiTi | 6.22 |
AlCo0.9CrFeNiMn0.9 | 6.75 |
Test ID | Run | Power Ratio A | Scan Speed Ratio B | Thickness C | (Approximate % of Powder Printed) |
---|---|---|---|---|---|
P25Speed003T2 | 1 | − | − | − | 10 |
P30Speed003T2 | 2 | + | − | − | 20 |
P25Speed005T2 | 3 | − | + | − | 8 |
P30Speed005T2 | 4 | + | + | − | 12 |
P25Speed003T4 | 5 | − | − | + | 13 |
P30Speed003T4 | 6 | + | − | + | 9 |
P25Speed005T4 | 7 | − | + | + | 8 |
P30Speed005T4 | 8 | + | + | + | 8 |
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Additive Manufactured Alloy Stoichiometry | Ecorr (V) | Log Icorr (A/cm2) |
---|---|---|
AlCoCrFeNiMn | −0.8838 | −5.15 |
CoCr1.3FeMnNi0.7 | −0.866 | −4.97 |
AlCoCr1.3FeNi1.3 | −0.724 | −5.19 |
AlCo0.9CrFeNiMn0.9 | −0.903 | −3.89 |
AlCoCrFeNiTi | −0.933 | −3.64 |
AlCo0.8CrFeNiTi | −0.874 | −3.75 |
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Sarswat, P.; Smith, T.; Sarkar, S.; Murali, A.; Free, M. Design and Fabrication of New High Entropy Alloys for Evaluating Titanium Replacements in Additive Manufacturing. Materials 2020, 13, 3001. https://doi.org/10.3390/ma13133001
Sarswat P, Smith T, Sarkar S, Murali A, Free M. Design and Fabrication of New High Entropy Alloys for Evaluating Titanium Replacements in Additive Manufacturing. Materials. 2020; 13(13):3001. https://doi.org/10.3390/ma13133001
Chicago/Turabian StyleSarswat, Prashant, Taylor Smith, Sayan Sarkar, Arun Murali, and Michael Free. 2020. "Design and Fabrication of New High Entropy Alloys for Evaluating Titanium Replacements in Additive Manufacturing" Materials 13, no. 13: 3001. https://doi.org/10.3390/ma13133001