Effective Adsorption of Diesel Oil by Crab-Shell-Derived Biochar Nanomaterials
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Activated Carbon
2.3. Characterization
2.4. Adsorption Experiments
3. Results and Discussion
3.1. Structure Characterization of Crab Shell Biochar
3.2. Effect of Adsorbent Dosage
3.3. Effect of Initial pH
3.4. Effect of Adsorbent Temperature
3.5. Effect of Contact Time
3.6. Adsorption Kinetics
3.7. Adsorption Isotherms
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | Surface Area (m2/g) | Pore Volume (m3/g) | Pore Size (nm) |
---|---|---|---|
CSB | 307 | 0.324 | 3.840 |
CSAB | 2441 | 1.682 | 1.937 |
Sample | Pseudo-First Order | Pseudo-Second Order | ||||
---|---|---|---|---|---|---|
qe, 1 (mg/g) | k1 (min−1) | R2 | qe, 2 (mg/g) | k2 (g/(mg·min) | R2 | |
CSAB | 79.82 | 0.1662 | 0.979 | 93.9 | 0.023 | 0.993 |
CSB | 65.02 | 0.15833 | 0.894 | 73.1 | 0.089 | 0.998 |
Sample | Freundlich Model | Langmuir Model | ||||
---|---|---|---|---|---|---|
n | KF | R2 | qm (mg/g) | KL | R2 | |
CSAB | 1.057 | 1.0617 | 0.999 | 57.74 | 0.0158 | 0.978 |
CSB | 1.146 | 0.993 | 0.992 | 30.71 | 0.0184 | 0.901 |
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Cai, L.; Zhang, Y.; Zhou, Y.; Zhang, X.; Ji, L.; Song, W.; Zhang, H.; Liu, J. Effective Adsorption of Diesel Oil by Crab-Shell-Derived Biochar Nanomaterials. Materials 2019, 12, 236. https://doi.org/10.3390/ma12020236
Cai L, Zhang Y, Zhou Y, Zhang X, Ji L, Song W, Zhang H, Liu J. Effective Adsorption of Diesel Oil by Crab-Shell-Derived Biochar Nanomaterials. Materials. 2019; 12(2):236. https://doi.org/10.3390/ma12020236
Chicago/Turabian StyleCai, Lu, Yan Zhang, Yarui Zhou, Xiaodie Zhang, Lili Ji, Wendong Song, Hailong Zhang, and Jianshe Liu. 2019. "Effective Adsorption of Diesel Oil by Crab-Shell-Derived Biochar Nanomaterials" Materials 12, no. 2: 236. https://doi.org/10.3390/ma12020236