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Utilization of Carbon Nanospheres in Photocatalyst Production: From Composites to Highly Active Hollow Structures

Research Group of Environmental Chemistry, Institute of Chemistry, University of Szeged, H-6720 Szeged, Tisza Lajos krt. 103, Hungary
Department of Applied and Environmental Chemistry, University of Szeged, H-6720 Szeged, Rerrich tér 1, Hungary
Institute of Process Engineering, Faculty of Engineering, University of Szeged, H-6725 Szeged, Moszkvai krt. 9, Hungary
Nanostructured Materials and Bio-Nano-Interfaces Center, Interdisciplinary Research Institute on Bio-Nano-Sciences, Babes-Bolyai University, RO–400271 Cluj-Napoca, Treboniu Laurian 42, Romania
Institute of Environmental Science and Technology, University of Szeged, H-6720, Szeged, Tisza Lajos krt. 103, Hungary
Department of Molecular Sciences, Faculty of Medicine, Iuliu Haţieganu University of Medicine and Pharmacy, RO–400012 Cluj-Napoca, Romania
Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, H-1111 Budapest, Hungary
Authors to whom correspondence should be addressed.
Materials 2019, 12(16), 2537;
Received: 8 July 2019 / Revised: 26 July 2019 / Accepted: 7 August 2019 / Published: 9 August 2019
PDF [8628 KB, uploaded 9 August 2019]


Titanium dioxide–carbon sphere (TiO2–CS) composites were constructed via using prefabricated carbon spheres as templates. By the removal of template from the TiO2–CS, TiO2 hollow structures (HS) were synthesized. The CS templates were prepared by the hydrothermal treatment of ordinary table sugar (sucrose). TiO2–HSs were obtained by removing CSs with calcination. Our own sensitized TiO2 was used for coating the CSs. The structure of the CSs, TiO2–CS composites, and TiO2–HSs were characterized by scanning electron microscopy (SEM), infrared spectroscopy (IR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and diffuse reflectance spectroscopy (DRS). The effect of various synthesis parameters (purification method of CSs, precursor quantity, and applied furnace) on the morphology was investigated. The photocatalytic activity was investigated by phenol model pollutant degradation under visible light irradiation (λ > 400 nm). It was established that the composite samples possess lower crystallinity and photocatalytic activity compared to TiO2 hollow structures. Based on XPS measurements, the carbon content on the surface of the TiO2–HS exerts an adverse effect on the photocatalytic performance. The synthesis parameters were optimized and the TiO2–HS specimen having the best absolute and surface normalized photocatalytic efficiency was identified. The superior properties were explained in terms of its unique morphology and surface properties. The stability of this TiO2–HS was investigated via XRD and SEM measurements after three consecutive phenol degradation tests, and it was found to be highly stable as it entirely retained its crystal phase composition, morphology and photocatalytic activity. View Full-Text
Keywords: titanium dioxide; carbon spheres; hollow structures; composite; visible light; photocatalysis; phenol titanium dioxide; carbon spheres; hollow structures; composite; visible light; photocatalysis; phenol

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Gyulavári, T.; Veréb, G.; Pap, Z.; Réti, B.; Baan, K.; Todea, M.; Magyari, K.; Szilágyi, I.M.; Hernadi, K. Utilization of Carbon Nanospheres in Photocatalyst Production: From Composites to Highly Active Hollow Structures. Materials 2019, 12, 2537.

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