The Preparation and Chemical Structure Analysis of Novel POSS-Based Porous Materials
Abstract
:1. Introduction
2. Experimental Part
2.1. Materials
2.1.1. The Synthesis of OPS
2.1.2. The Preparation of the Porous Materials
2.2. Characterization
3. Results and Discussion
3.1. The Preparation and Morphology Control of the Porous Materials
3.2. The Chemical Structure of the Porous Materials
3.2.1. FTIR
3.2.2. NMR
3.2.3. XPS
3.3. Thermal Properties (TGA)
3.4. Further Discussion
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Samples | Raw Materials | Reaction Time (h) | Active Hydrogen Source | Reaction Temperature (°C) |
---|---|---|---|---|
A | OPS | 20 | H2O | 40 |
B | OPS | 20 | CH3OH | 40 |
C | T7-POSS | 20 | H2O | 40 |
Signal | Structure | Binding Energy (eV) |
---|---|---|
Peak A | Ph–CH2–OH | 288.56 |
Peak B | Ph–CH2–Ph | 286.07 |
Peak C | –C6H6 | 284.66 |
Peak D | Si–OCH2–Ph | 290.15 |
Samples | T90 (°C) | Tmax (°C) |
---|---|---|
OPS | 459.84 | 456.02/539.18 |
A | 402.08 | 550.42 |
T7-POSS | 564.50 | 211.45/597.73 |
C | 343.47 | 420.91 |
No. | Reaction Time (h) | Reaction Temperature (°C) | Raw Materials (POSS) | Solvents | Other Conditions | References |
---|---|---|---|---|---|---|
1 | 48 | 80 | OVS | THF/Et3N | Pd(OAc)2/PPh3 | [24] |
2 | 48 | 100 | OVS | DMF/Et3N | Pd(OAc)2/P(o-CH3Ph)3 | [25] |
3 | 24 | Reflux | OVS | CS2 | AlCl3, Argon | [26] |
4 | 48 | 100 | OVS | DMF/Et3N | Pd(OAc)2/P(o-CH3Ph)3 | [40] |
5 | 24 | 60 | OPS | CHCl3 | AlCl3 | [38] |
6 | 24 | Reflux | OVS | CS2 | AlCl3, Stoichiometric benzene | [41] |
7 | 20 | 40 | OPS or T7-POSS | DCM | AlCl3 | This work |
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Yang, X.; Yin, G.; Li, Z.; Wu, P.; Jin, X.; Li, Q. The Preparation and Chemical Structure Analysis of Novel POSS-Based Porous Materials. Materials 2019, 12, 1954. https://doi.org/10.3390/ma12121954
Yang X, Yin G, Li Z, Wu P, Jin X, Li Q. The Preparation and Chemical Structure Analysis of Novel POSS-Based Porous Materials. Materials. 2019; 12(12):1954. https://doi.org/10.3390/ma12121954
Chicago/Turabian StyleYang, Xiaomei, Guangzhong Yin, Zhiyong Li, Pengfei Wu, Xiaopei Jin, and Qifang Li. 2019. "The Preparation and Chemical Structure Analysis of Novel POSS-Based Porous Materials" Materials 12, no. 12: 1954. https://doi.org/10.3390/ma12121954