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Materials 2018, 11(11), 2208;

Dielectric, Ferroelectric, and Magnetic Properties of Sm-Doped BiFeO3 Ceramics Prepared by a Modified Solid-State-Reaction Method

Electric Power Research Institute, China Southern Power Grid Co., Ltd., Guangzhou 510080, China
School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
Author to whom correspondence should be addressed.
Received: 8 October 2018 / Revised: 28 October 2018 / Accepted: 5 November 2018 / Published: 7 November 2018
PDF [2838 KB, uploaded 7 November 2018]


Sm-doped BiFeO3 (BFO) material was prepared using a modified solid-state-reaction method, which used fast heating and cooling during the sintering process. The Sm doping level varied between 1 mol % to 8 mol %. Processing parameters, such as sintering temperature and annealing temperature, were optimized to obtain high-quality samples. Based on their dielectric properties, the optimum sintering and annealing temperatures were found to be 300 °C and 825 °C, respectively. Leakage-free square-shaped ferroelectric hysteresis loops were observed in all samples. The remnant polarization was maximized in the 5 mol %-doped sample (~35 μC/cm2). Furthermore, remnant magnetization was increased after the Sm doping and the 8 mol%-doped sample possessed the largest remnant magnetization of 0.007 emu/g. Our results demonstrated how the modified solid-state-reaction method proved to be an effective method for preparing high-quality BiFeO3 ceramics, as well as how the Sm dopant can efficiently improve ferroelectric and magnetic properties. View Full-Text
Keywords: BFO; Sm dopant; dielectric; ferroelectric; magnetic BFO; Sm dopant; dielectric; ferroelectric; magnetic

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Zhang, F.; Zeng, X.; Bi, D.; Guo, K.; Yao, Y.; Lu, S. Dielectric, Ferroelectric, and Magnetic Properties of Sm-Doped BiFeO3 Ceramics Prepared by a Modified Solid-State-Reaction Method. Materials 2018, 11, 2208.

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