1. Introduction
The extensive use of fossil fuels has led to global warming, making it crucial to reform the current energy consumption structure. In the post-carbon energy era, energy conservation, emission reduction, and the efficient use of energy have become common goals. China’s 14th Five-Year Plan proposes to further strengthen the efficient use of energy. Thermal storage technology can effectively address the contradiction between time and intensity mismatch in the supply and demand of thermal energy, thus avoiding energy waste and improving energy utilization. Phase change thermal storage and heat exchange technology have been widely used in solar thermal power generation, solar medium, and low-temperature thermal utilization. Specifically, this technology can be used to improve solar thermal electric power generation, the low-temperature heat utilization of solar energy, the recycling and utilization of waste heat in exhaust fumes, electric thermal storage heating for peak shaving, and the reduction of building energy consumption. Therefore, researchers have focused on improving the thermal efficiency of phase change thermal storage heat exchangers, reducing heat loss, and increasing the utilization rate of heat sources.
Compared with ordinary energy storage methods, the solid/liquid phase change of phase change thermal storage materials can exhibit large heat storage capacity per unit mass, small volume change rate during phase change, easy control, and a stable output temperature. Organic phase change materials have low thermal conductivity, which can affect the heat transfer rate during the heat storage/release process. In addition, a thermal storage trap can occur, caused by the rapid solidification of phase change materials on the side of the heat transfer tube during heat release, leading to blocked heat dissipation at the edge. Issues such as local overheating can also occur along the direction of high-temperature heat transfer fluid. Thermal storage systems face certain problems, such as efficiency, stability, reliability, and other key performance aspects, which serve as the main bottlenecks faced by new thermal storage technologies in practical applications.
With technological improvements, phase change heat storage and heat exchange technologies have rapidly developed [
1]; however, most research has focused on optimizing specific structures in heat exchangers, including internal ring ribs, external fins, and spiral forms. Cao et al. [
2] created a cross-fractal metal and snowflake heat exchanger model that can be used to conduct theoretical modeling and numerical research on the phase change material (PCM) melting process in a heat exchanger, as shown in
Figure 1.
Zhao et al. [
3] investigated direct contact thermal storage technology by building a PCM jet breaker test bed, while Cui et al. [
4] used ANSYS simulation software (version 17.0) to study the heat storage and release performance of finned tube phase change energy storage heat exchangers as well as to analyze the phase change process and heat transfer laws of phase change materials. In addition, Zhou et al. [
5] used FLUENT software (version 17.0) to numerically simulate the heat transfer process of paraffin in a rectangular heat storage unit and found that increasing the temperature difference between the heat transfer fluid and paraffin significantly improved the heat storage and release efficiency. Zhang et al. [
6] conducted a study on the heat storage and release of phase change materials encapsulated in a sleeve-type heat exchanger within a toroidal space. The study found that during heat release, the phase change material on the side of the heat exchange tube solidified too quickly, leading to issues such as the obstruction of heat dissipation at the edges and local overheating along the direction of the high-temperature heat exchange fluid. Lin et al. [
7] proposed a heat exchanger with a heat storage mechanism based on latent heat storage, which was formed by seam welding the edges of two steel plates and then welding the plates together. This resulted in a layered arrangement of heat transfer channels and heat storage materials. The complex flow channel distribution enhanced the turbulence intensity and secondary flow of the fluid, resulting in better thermal performance. Zhu et al. [
8] proposed increasing the heat dissipation buffer space of heat exchangers by filling the gap between the heat exchanger and the shell with phase change materials for optimizing phase change heat exchangers. The heat dissipation efficiency of the coil heat exchanger was improved by 3.8% by adding inner ring ribs in the coil heat exchanger channel.
Chen et al. [
9] drew on the design concept of plate heat exchangers and fully considered the thermophysical properties of phase change materials to design a new type of phase change thermal storage heat exchanger, as shown in
Figure 2. The study found that the time required for the phase change material to complete the phase change was significantly affected by natural convection, which accelerated the phase change rate of the phase change material. The effect of natural convection was greater on the heat storage process than on the heat release process, and the role of natural convection was most intense during the heat storage and release process. The ribs expanded the heat transfer area between the phase change material and the heat transfer fluid, which also accelerated the phase change rate of the phase change material. Natural convection and the fins could both compensate for the low thermal conductivity of phase change materials.
Beyne et al. [
10] adopted the same assumptions as the analytical model of Stefan’s problem, established a numerical model, and verified the analytical results. The final analytical solution could be simplified into a finite set of parameters, which could serve as a basis for experimental data reference for latent heat storage heat exchangers. Gürel et al. [
11] simplified the numerical analysis into two dimensions based on the finite volume method. The simulation results showed that under the same phase change material, boundary conditions, and geometric characteristics, the time required for the phase change material to fully solidify could be reduced by up to 63% compared with a cylindrical latent heat storage system with the same phase change material volume. Kumar et al. [
12] studied a thermal storage device composed of a spiral coil heat exchanger and twisted copper wire, as shown in
Figure 3. The study found that organic PCMs exhibited higher efficiency and stability during the charging and discharging process. The instantaneous efficiency of the thermal storage device was highest at low flow rates and lowest at high flow rates, thus making it necessary to balance flow rate and heat transfer efficiency.
Radomska et al. [
13] analyzed published studies on the influence of heat exchanger structure on the melting and solidification time of phase change thermal storage materials. The study determined that by changing the geometric parameters of the heat exchanger or using fins, metal foams, heat pipes, and various phase change materials, the phase change time of the phase change material in the heat exchanger could be shortened. Das et al. [
14] summarized research on enhancing the thermal conductivity of phase change materials by compounding phase change materials and doping high thermal conductivity materials. Toffoletti et al. [
15] simulated through heat and mass balances with a thorough heat transfer analysis the charging and discharging phases of the Ice Thermal Energy Storage, specifically adapted to the operating conditions in the water tank.
In summary, current research on thermal storage and heat exchange systems has mainly focused on simplifying their non-uniform, anisotropic, and other characteristics to form a symmetrical two-dimensional steady-state model. Subsequently, the influence of the velocity field, initial temperature, heat exchange tube structure, and solid/liquid phase distribution of phase change thermal storage materials on heat exchange systems in thermal storage and heat exchange systems was calculated and analyzed. However, very few studies have conducted a theoretical analysis and experimental research on the thermal performance of entire phase change thermal storage and heat exchange systems, which makes it difficult to accurately analyze the overall heat exchange efficiency of phase change thermal storage and heat exchange systems.
Wang et al. [
16] established two-dimensional physical models of smooth-tube and corrugated-tube heat exchangers in an ice storage tank. The effects of structural parameters, including the pitch and corrugation height, on ice storage performance were comprehensively analyzed. The results indicated that the duration of ice storage using the corrugated-tube heat exchanger was shortened by 7.1% relative to the traditional smooth-tube heat exchanger; this occurred because corrugations disrupt the development of the boundary layer and strengthen fluid mixing. By changing the traditional parameters of the heat exchanger, multiple sets of simulated data were obtained to form a control group, and the structural characteristics of the heat exchanger with the best performance were obtained. Using multi-physical field simulation software, the influence of different heat exchange tube structures, fins, and cooling fluid flow rates on the thermal performance of the heat exchanger was analyzed. The influence of each structure on the heat transfer results during the heat transfer process was analyzed. By optimizing the structure of the heat exchanger, a phase change thermal storage heat exchanger with excellent performance was obtained. The research results could serve as a reference for subsequent research on the structure of heat exchangers.