1. Introduction
Compressed air is the most commonly used energy source in modern industrial enterprises [
1]. The advantages of compressed air over other types of energy sources include its relative safety, ease of production, and the ability to accumulate and store it in high-pressure tanks [
2]. Compressed air energy is commonly used for powering pneumatic equipment and tools.
Compressed air can also be used as part of a technological process, for example, for abrasive surface treatment, transporting bulk materials, cooling equipment, or cutting tools. However, compressed air is a source of large amounts of condensate, which is not desirable if trapped in pneumatic equipment, when in contact with abrasive materials, or in contact with food [
3]. Therefore, in addition to basic parameters such as capacity and pressure, compressed air must meet certain quality parameters. One of the main quality parameters is the humidity level—the lower the humidity, the higher the quality of compressed air.
The quality of compressed air is classified according to the international standard ISO 8573-1:2010 [
4], which separates quality classes based on humidity and is determined by the pressure dew point.
To solve the problem of removing water vapour from compressed air, special equipment is used, which includes cyclone separators, air aftercoolers, refrigeration dryers, membrane dryers, and cold or hot regeneration adsorption dryers [
5]. The use of one or another type of equipment to reduce the humidity in compressed air depends on the technological requirements or economic feasibility. Each of the above-mentioned devices has its own maximum capacity to dry compressed air and achieve a certain dew point. Most production processes use compressed air with a dew point of +3 °C. To achieve this parameter, refrigeration dryers are usually used. Dehumidification is based on the principle of cooling compressed air, followed by the process of water vapour turning into liquid; then, the condensate is removed using separation devices. The main disadvantage of such dehumidifiers is the use of ozonating refrigerants R134 or R404 [
6], which, moreover, easily leak through possible leaks in the refrigeration cycle, and afterwards the dehumidifier becomes inoperable and requires repair work.
Compressed air is produced by a compressor; however, the temperature of the compressed air after the compressor can reach 80 °C, which is unacceptable for use in compressed air dryers. Therefore, intermediate aftercoolers are used to reduce the compressed air temperature to a temperature of 10 °C higher than the ambient temperature.
After leaving the aftercooler, the compressed air contains residual moisture in the form of vapour, which condenses and settles in the system, leading to corrosion. That is why the use of dehumidifiers is necessary; however, the disadvantages of refrigeration dryers include the use of ozonating refrigerants R134 or R404 [
7].
The following is a brief analysis of alternative refrigeration systems that can theoretically be used to implement compressed air cooling in pneumatic systems of industrial enterprises.
To reduce the load on electrical networks when cooling and conditioning large rooms or apartment buildings, the authors in [
8] propose to use the method of expansion cooling, which allows the temperature of a liquid or gas to decrease as a result of its volume expansion or pressure reduction. This process can be realised by producing compressed air using air compressors during periods of low demand or high-renewable-energy production and then storing it in underground caves or high-pressure containers. The compressed air is then used to cool the premises using throttle expansions and heat exchangers without the need for standard air conditioning or ventilation systems. However, this process is only possible if there is significant renewable energy production and large-scale compressed air storage.
To achieve very low temperatures of around —140 °C in industrial applications, a Brayton cryocooler can be used, which uses nitrogen as the working fluid [
9,
10]. The Brayton cryocooler can be used for air conditioning, medical applications (e.g., storage of COVID-19 vaccines), and in the food industry to freeze various food products at very low temperatures. The Brayton refrigeration cycle is based on the principle of expanding compressed gas, in this case nitrogen, in a turbine. The main equipment that makes up the regenerative cycles is a compressor and a displacement piston, separated by an evaporator, a regenerator, and a condenser. The use of the Brayton cycle for cryogenic applications—combined with the use of nitrogen as the working fluid—seems promising in many respects but most research is focused on numerical design and optimisation proposals that are not supported by experimental data, and the cryogenic capacities tested for nitrogen Brayton cycles hardly exceed the cooling capacities of more than a few hundred watts, reaching cryogenic temperatures under steady-state conditions. Another significant disadvantage of the Brayton cryocooler is the high cost of the initial unit (turbine and centrifugal compressor), which can reach around EUR 70,000. The authors of the article [
10] present the results of an energy analysis of the performance of the Brayton cryocooler prototype. To simulate the cooling effect, an electric heater with a power of 15.6 kW was installed in the design of the prototype, and the power of the electric motor for the operation of the piston compressor was 53.7 kW.
In study [
11], the Hampson cryocooler is proposed to obtain low temperatures, which operates on the principle of a Joule–Thompson cryocooler and uses a spiral heat exchanger with argon as a working medium. The spiral heat-exchanger recuperator consists of three parts: an outer tube—a Monel alloy shell; an inner tube—a Monel alloy mandrel; and a stainless-steel capillary tube that spirals around the mandrel to carry high-pressure liquids. The heat exchanger also uses two types of fins with different geometrical parameters: firstly, fins with a dense fin pattern, and then the use of fins with a sparse pitch. This allows for a 9% increase in cooling capacity. The main disadvantage of the Hampson cryocooler is the mandatory use of hermetic gas cylinders with argon or nitrogen gases, which increases the cost of the cryocooler and requires special conditions of use.
Another interesting cooling process is discussed in the study [
12]. The authors describe a model of a dehumidification process called Claridge–Culp–Liu (CCL), which is a new and efficient approach for removing water vapour from air using a combination of membrane separation, vacuum compression, and sub-atmospheric condensation. The basic theory behind this process is to separate water vapour from the humid air flowing through one side of a membrane by applying a partial vacuum to the opposite side of the membrane and, then, compressing the water vapour for saturation pressure at the humid-ambient-air thermometer temperature to facilitate condensation. The cooling process has a fundamental efficiency limit that approaches the Carnot limit but requires between 26% and 56% of the energy required for a Carnot vapour compression system. The condenser can be cooled by either ambient air or cooling tower water, as is commonly performed in a compression refrigeration system. A vacuum pump for this system is required to remove non-condensables from the original system as well as non-condensables that seep through the membrane during operation. The CCL dehumidification system has the following advantages: (1) No use of a HFC refrigerant. (2) Direct isothermal control of the setpoint humidity coefficient. (3) Maximum capacity occurs at designed conditions. (4) The system generates clean water extracted from the air as a by-product. However, effective dehumidification still requires the use of cooling towers, which increases the cost of the process and requires special operating conditions. In addition, the CCL cooling process is currently in the design phase and is not used in practice.
Existing refrigerators and freezers in households account for around 6% of electricity generated globally. These cooling systems typically use R134a gas refrigerant. In the article [
13], the authors experimentally investigate a dual-temperature R290/R600a refrigeration system based on a split condensation approach with two evaporators. The study demonstrated that the use of R290/R600a in a home refrigerator can reduce energy consumption by 12.3% compared to R134a. The main components of this refrigeration system—which uses an azeotropic blend of refrigerants—include a compressor, two condensers, a sub-cooler, a phase separator, two suction-line heat exchangers, two needle-metering valves as expansion devices, and two parallel evaporators installed in their respective cabinets. Theoretical results showed the potential for performance improvement compared to a conventional refrigeration cycle.
A popular type of refrigeration system is the thermally driven ejector refrigerator, which is powered by heat that can be generated from industrial waste heat, solar water heaters, geothermal energy, etc. Ejector chillers are simple in design and easy to operate and maintain. An ejector cooler consists of a generator, evaporator, ejector, condenser, liquid pump, and measuring instruments. An immersion electric heater is used to generate heat for the generator and evaporator. The working fluid in such refrigeration systems is usually R141b gas, which is a type of HCFC refrigerant. In an ejector refrigeration system, the ejector is an important piece of equipment that affects the efficiency of the refrigeration cycle. The ejector used in a refrigeration system is similar to a mechanical compressor, so it is known as a ‘thermal compressor’ because it is powered by heat. The performance of an ejector refrigeration system depends on the geometry of the ejector nozzle, namely the ratio of the nozzle area to the operating conditions [
14].
Analysing various variants of cooling systems for premises or technological processes in industry, described in studies [
8,
10,
11,
12,
13,
15], it can be concluded that these systems are difficult to adapt for cooling compressed air in pneumatic systems of industrial enterprises. Firstly, they require the mandatory availability of large-volume compressed air storage facilities in the form of underground storage facilities or large-sized above-ground compressed air tanks. Secondly, some technologies involve the use of a cooling tower, which is also expensive and requires special industrial construction. Thirdly, the use of various types of cooling gases—such as R290, R600a, R141b, nitrogen, or argon—are harmful for the environment or require special equipment and storage conditions.
Thus, this article is devoted to the development of a model of compressed air drying based on the principle of a refrigeration dryer but instead of gas refrigerants, the method proposed is to use cooled compressed air with a temperature below 273 K as a cooling medium. Thus, the objective of the research described in this article is to study the possibility of replacing harmful cooling gases with a neutral type of coolant. To conduct this study, a test bench was designed and manufactured, the description of which is presented in this manuscript. The results obtained are presented in the form of graphs that show the potential use of compressed air energy for the process of cooling the main stream of warm compressed air after the compressor to a temperature that will ensure the quality of compressed air at the level of class 4, for a dew point of +3 °C under pressure, in accordance with the standards specified in ISO 8573-1:2010.
The main objective of this study is to develop a model of a compressed air dryer that will operate similarly to a standard refrigeration dryer. The fundamental difference will be the replacement of ozonating R134 or R404 refrigerants with cooled compressed air with a temperature below 0 °C. The process of heat exchange between the main warm and humid compressed air stream from the compressor and the pre-cooled air stream, which will act as a refrigerant, will then take place.
3. Results
This study was carried out in three modes to determine the mode of compressed air outflow from the receiver, which would result in the lowest temperature T2 after the ball valve: a constantly partially open ball valve, a constantly fully open ball valve, and a mode in which the ball valve was opened quickly and completely to discharge the entire volume of compressed air from the receiver.
During the first study, the ball valve was partially opened and the pressure in the receiver P2 was maintained in the range of 0.601–0.697 MPa (
Figure 3) due to the constant supply of compressed air from the CompAir START-031 compressor (item 2,
Figure 4). A slight increase in pressure is due to the fact that in manual mode it is difficult to balance the volume of air entering and leaving the receiver through the partially covered throttle but this did not fundamentally affect the results.
In the diagram in
Figure 4, we can see the temperature changes at the inlet and outlet of the heat exchanger. The temperatures T3 and T4 remained almost unchanged, averaging 29.1 °C and 27.2 °C, respectively. The air temperature after the T2 throttle dropped slightly from 25.2 °C to 21 °C. The cooled air under pressure T1 was also at a fairly high level in the range of 15.1–18.3 °C. This means that there was no influence of the air after the T2 choke on the T1 air temperature, and the difference between T3 and T1 is due to the heat inertia of the heat exchanger.
For the second study, we used the mode of a constant compressed air outlet from the receiver through a fully open ball valve, while compressed air was constantly supplied to the receiver from the CompAir START-031 screw compressor (item 2,
Figure 2). In this situation, the pressure in the receiver P2 was almost equal to the atmospheric pressure and was at the level of 0.039 MPa (
Figure 5). Using the graph shown in
Figure 6, we can trace the temperature values at the inlet and outlet of the heat exchanger. As in the first experiment, temperatures T3 and T4 remained almost unchanged and averaged 28.1 °C and 25.4 °C, respectively. At the same time, the temperatures of T1 and T2 also remained unchanged and almost did not differ, and were in the range of 12–12.6 °C. The difference between the temperatures T3 and T1 was 15.9 °C and was not due to the heat energy of the heat exchanger itself but rather to the influence of the air T2 after the throttle.
The third experiment was based on the method of rapid discharge of the entire volume of compressed air from the receiver. To perform this, the receiver was filled with compressed air to a pressure of P2 of 0.906 MPa (
Figure 7) with the outlet ball valve completely closed. After the receiver was filled, the valve was quickly and completely opened, and compressed air was released from the receiver within 76 s until the pressure dropped to P2 0.041 MPa (
Figure 7). This throttling mode allowed us to obtain the desired results of the inlet and outlet temperatures of the heat exchanger. The air temperature after the throttle T2 briefly dropped to −18.8 °C, which in turn facilitated a reduction in the temperature of T1 to +6.8 °C (
Figure 8); this temperature is in the range of compressed air temperatures provided by refrigeration dryers with R134 or R404 refrigerants.
Table 2 summarises the parameters obtained during all three experiments.
Using the temperature of the compressed air after cooling in the heat exchanger during the third experiment, we can calculate how much moisture can be condensed. For the sake of convenience, let us take T1 = 7 °C.
For calculation of the mass flow rate of water vapour remaining in the compressed air after the cooler, we first find the moisture content of the air sucked in by the compressor for compression [
19].
The vapour pressure p
v can be derived from the saturation vapour pressure p
vs:
where φ is the relative vapour pressure (60% at the time of the experiment); and p
v = 0.60 × 17.04 mbar (p
vs value at 15 °C, see Table on (p. 134, [
20])).
Dry air pressure is calculated from the formula:
where p
ha = 1.013 bar (the air enters the compressor at normal atmospheric pressure).
We find that pa = 1.013 − 0.010224 = 1.002776 bar absolute.
Where Pha—humid air pressure: Pa, dry air pressure; Pv, water vapour pressure.
The water content X of the sucked-in air is found by means of the following formula:
X = 0.622 = 0.01019 kg water vapour/kg dry air
In order to calculate the water content per m
3 of sucked-in air, we use the following equation:
where ρ
v is the water vapour density; Rv = 461.5 J/(kg·K) is the gas constant; T = 15 °C is the absolute ambient temperature.
Let us find the amount of moisture that will be released from the compressed air after cooling in the heat exchanger.
After the aftercooler the air is saturated, φ = 1 and pv = pvs.
We can calculate P
a and X as follows:
where p
v = 10.01 mbar (p
vs value at 7 °C, see Table on (p. 134, [
20])); p
ha = 6.2 bar—air pressure after the compressor.
Then we find water vapour of dry air:
Next, we calculate the water vapour density that will be released from the compressed air after cooling in the heat exchanger:
Calculated to FAD conditions (1 bar absolute inlet pressure):
This means that in the aftercooler 7.69 − 1.25 = 6.44 g condensate per m3 will be formed.
5. Conclusions
In this article, a model of compressed air drying based on the principle of operation of a refrigeration dryer was considered but instead of R134 or R404 gas refrigerants, chilled compressed air was used as a cooling medium with a temperature below 0 °C. The objective of the study described in this article was to investigate the possibility of replacing harmful cooling gases with a neutral type of coolant using compressed air energy.
To implement the task, a test bench was designed and manufactured (
Figure 2), consisting of two screw compressors, an air receiver, a ball valve as a throttle, a plate heat exchanger, temperature sensors, a pressure sensor, and a microprocessor controller.
To obtain an air flow with a temperature below 0 °C, one of the most widely available methods was used, namely the Joule–Thompson effect, which allowed the compressed air temperature to be reduced to −18.8 °C while the compressed air was rapidly exiting the receiver through the throttling device. In the plate heat exchanger, short-term heat exchange between warm and humid compressed air and cooled air took place, which reduced the compressed air temperature to +6.8 °C. This temperature is within the range of 1.7 °C to 10 °C provided by standard refrigeration dryers that use R134 or R404 gases as refrigerants, and it is also close to +3 °C, which can ensure compressed air quality at the level of class 4 according to ISO 8573-1:2010.