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Open AccessArticle

Novel Shape-Stabilized Phase Change Material with Cascade Character: Synthesis, Performance and Shaping Evaluation

Departament de Ciència de Materials i Química Física, Universitat de Barcelona, C/Martí i Franquès 1, 08028 Barcelona, Spain
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Academic Editor: Antonio Rosato
Energies 2021, 14(9), 2621; https://doi.org/10.3390/en14092621
Received: 18 March 2021 / Revised: 13 April 2021 / Accepted: 16 April 2021 / Published: 3 May 2021
(This article belongs to the Special Issue Phase Change Materials for Thermal Energy Storage Applications)
Thermal Energy Storage (TES) materials, such as Phase Change Materials (PCMs) are proven to enhance the energy efficiency in many fields, such as automotive and building sectors, which correspond to the most energy intensive ones. Shape-stabilized PCM and cascade PCM are procedures to overcome the most important barriers when PCMs are applied since PCMs need to be encapsulated for their technical use: the leakage of the liquid phase, corrosion, low heat transfer and narrow temperature of application. In the present study, a novel shape stabilized PCM with cascade performance (cascade shape stabilized phase change material, CSS-PCM) is synthesized via dissolution, which allows up to 60 wt.% of a paraffin-PCM in the final composition. The novel CSS-PCM is based on a biopolymer, the polycaprolactone (PCL), a low melting temperature polyester as polymeric matrix and RT27 and Micronal DS 5040 acting as PCM. To evaluate the performance of the new TES materials developed, several techniques have been used: Differential Scanning Calorimetry (DSC), and Fourier-Transformed Infrared (FT-IR) spectroscopy were used to evaluate the thermophysical properties and the chemical properties of the different formulations. The CSS-PCM show an increment of storage capacity by increasing the PCM content, and the thermal reliability was also tested: some of the CSS-PCM formulations were stable for up to 500 thermal cycles. Finally, as a potential application of the new polymeric-based PCM 3D, a printing attempt was performed in order to analyze the viability of the formulations to be used as 3D printing material as a first proof of concept. View Full-Text
Keywords: thermal energy storage; phase change material; 3D printing; cascade-PCM; shape-stabilized PCM; cascade shape-stabilized PCM thermal energy storage; phase change material; 3D printing; cascade-PCM; shape-stabilized PCM; cascade shape-stabilized PCM
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MDPI and ACS Style

Salgado-Pizarro, R.; Padilla, J.A.; Xuriguera, E.; Barreneche, C.; Fernández, A.I. Novel Shape-Stabilized Phase Change Material with Cascade Character: Synthesis, Performance and Shaping Evaluation. Energies 2021, 14, 2621. https://doi.org/10.3390/en14092621

AMA Style

Salgado-Pizarro R, Padilla JA, Xuriguera E, Barreneche C, Fernández AI. Novel Shape-Stabilized Phase Change Material with Cascade Character: Synthesis, Performance and Shaping Evaluation. Energies. 2021; 14(9):2621. https://doi.org/10.3390/en14092621

Chicago/Turabian Style

Salgado-Pizarro, Rebeca; Padilla, Jose A.; Xuriguera, Elena; Barreneche, Camila; Fernández, Ana I. 2021. "Novel Shape-Stabilized Phase Change Material with Cascade Character: Synthesis, Performance and Shaping Evaluation" Energies 14, no. 9: 2621. https://doi.org/10.3390/en14092621

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