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Volume 2024
Issue 4
10.3390/M1892
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This is an early access version, the complete PDF, HTML, and XML versions will be available soon.
Short Note

[(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine

by
Salvador Vilchis-Valdés
1,2,
Alberto Cedillo-Cruz
1,
Marco A. García-Eleno
1,2,
Diego Martínez-Otero
1,3 and
Erick Cuevas-Yañez
1,2,*
1
Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, Mexico
2
Facultad de Química, Universidad Autónoma del Estado de México, Paseo Colon esq. Paseo Tollocan, Toluca 50120, Estado de México, Mexico
3
Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior S. N., Ciudad Universitaria, Coyoacán, Ciudad de México 04510, Mexico
*
Author to whom correspondence should be addressed.
Molbank 2024, 2024(4), M1892; https://doi.org/10.3390/M1892
Submission received: 14 August 2024 / Revised: 27 September 2024 / Accepted: 29 September 2024 / Published: 30 September 2024
Versions Notes

Abstract

The formation of a N,1,1-triaryl imine derived from (2-chlorophenyl)-bis-(4-fluorophenyl)methanol is reported. The title compound is formed from a consecutive process which involves a nucleophilic substitution and subsequent Schmidt reaction. A description of the synthesized compound’s NMR spectra is presented and the structure was unambiguously established by X-ray analysis. A Hirshfeld surface analysis is also included, confirming the presence of intermolecular H···F interactions involved in crystal packing.
Keywords: imine; azide; rearrangement; triarylmethyl alcohol; crystal structure imine; azide; rearrangement; triarylmethyl alcohol; crystal structure

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MDPI and ACS Style

Vilchis-Valdés, S.; Cedillo-Cruz, A.; García-Eleno, M.A.; Martínez-Otero, D.; Cuevas-Yañez, E. [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine. Molbank 2024, 2024, M1892. https://doi.org/10.3390/M1892

AMA Style

Vilchis-Valdés S, Cedillo-Cruz A, García-Eleno MA, Martínez-Otero D, Cuevas-Yañez E. [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine. Molbank. 2024; 2024(4):M1892. https://doi.org/10.3390/M1892

Chicago/Turabian Style

Vilchis-Valdés, Salvador, Alberto Cedillo-Cruz, Marco A. García-Eleno, Diego Martínez-Otero, and Erick Cuevas-Yañez. 2024. "[(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine" Molbank 2024, no. 4: M1892. https://doi.org/10.3390/M1892

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