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Short Note

6,6′-Di-(2″-thiophenol)-2,2′-bipyridine

School of Chemistry and Chemical Engineering, Guangzhou University, No. 230 Wai Huan Xi Road, Higher Education Mega Center, Guangzhou 510006, China
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Author to whom correspondence should be addressed.
Academic Editor: Oleg A. Rakitin
Molbank 2022, 2022(2), M1355; https://doi.org/10.3390/M1355
Received: 4 March 2022 / Revised: 21 March 2022 / Accepted: 21 March 2022 / Published: 24 March 2022
This short note describes the synthesis of compound 6,6′-di-(2″-thiophenol)-2,2′-bipyridine from its methyl phenyl sulfane precursor via deprotection of the methyl groups. The product as well as the intermediate in the synthetic route have been characterized by UV-Vis spectroscopy, 1H- and 13C-NMR spectroscopy, FT-IR spectroscopy, and HR-MS analysis. This work presents a rare example of tetradentate chelators that bears pyridyl backbones and thiophenol donors for the coordination with 3d-transition metal cations. View Full-Text
Keywords: thiophenol; bipyridine; tetradentate ligand; hydrogenase; transition metal; coordination thiophenol; bipyridine; tetradentate ligand; hydrogenase; transition metal; coordination
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MDPI and ACS Style

Huang, Y.; Tong, L. 6,6′-Di-(2″-thiophenol)-2,2′-bipyridine. Molbank 2022, 2022, M1355. https://doi.org/10.3390/M1355

AMA Style

Huang Y, Tong L. 6,6′-Di-(2″-thiophenol)-2,2′-bipyridine. Molbank. 2022; 2022(2):M1355. https://doi.org/10.3390/M1355

Chicago/Turabian Style

Huang, Yan, and Lianpeng Tong. 2022. "6,6′-Di-(2″-thiophenol)-2,2′-bipyridine" Molbank 2022, no. 2: M1355. https://doi.org/10.3390/M1355

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