6,6′-Di-(2″-thiophenol)-2,2′-bipyridine
School of Chemistry and Chemical Engineering, Guangzhou University, No. 230 Wai Huan Xi Road, Higher Education Mega Center, Guangzhou 510006, China
*
Author to whom correspondence should be addressed.
Academic Editor: Oleg A. Rakitin
Molbank 2022, 2022(2), M1355; https://doi.org/10.3390/M1355
Received: 4 March 2022
/
Revised: 21 March 2022
/
Accepted: 21 March 2022
/
Published: 24 March 2022
This short note describes the synthesis of compound 6,6′-di-(2″-thiophenol)-2,2′-bipyridine from its methyl phenyl sulfane precursor via deprotection of the methyl groups. The product as well as the intermediate in the synthetic route have been characterized by UV-Vis spectroscopy, 1H- and 13C-NMR spectroscopy, FT-IR spectroscopy, and HR-MS analysis. This work presents a rare example of tetradentate chelators that bears pyridyl backbones and thiophenol donors for the coordination with 3d-transition metal cations.
View Full-Text
Keywords:
thiophenol; bipyridine; tetradentate ligand; hydrogenase; transition metal; coordination
▼
Show Figures
Figure 1
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
- Supplementary File 1:
PDF-Document (PDF, 342 KiB)
- Supplementary File 2:
3D structure (MOL, 3 KiB)
Display in JSmol Viewer
3D structure generated by CORINA Classic by MN-AM. - Supplementary File 3:
INCHI-Document (INCHI, 908 B)
- Supplementary File 4:
MOL-Document (MOL, 3 KiB)
Display in JSmol Viewer
- Supplementary File 5:
3D structure (MOL, 3 KiB)
Display in JSmol Viewer
3D structure generated by CORINA Classic by MN-AM. - Supplementary File 6:
INCHI-Document (INCHI, 888 B)
- Supplementary File 7:
MOL-Document (MOL, 3 KiB)
Display in JSmol Viewer
MDPI and ACS Style
Huang, Y.; Tong, L. 6,6′-Di-(2″-thiophenol)-2,2′-bipyridine. Molbank 2022, 2022, M1355. https://doi.org/10.3390/M1355
AMA Style
Huang Y, Tong L. 6,6′-Di-(2″-thiophenol)-2,2′-bipyridine. Molbank. 2022; 2022(2):M1355. https://doi.org/10.3390/M1355
Chicago/Turabian StyleHuang, Yan, and Lianpeng Tong. 2022. "6,6′-Di-(2″-thiophenol)-2,2′-bipyridine" Molbank 2022, no. 2: M1355. https://doi.org/10.3390/M1355
Find Other Styles
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.
