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Synthesis, Crystal Structure and Cyclic Voltammetric Behavior of N-aroyl-N′-(4′-cyanophenyl)thioureas

1
Department of Chemistry, Faculty of Arts and Sciences, Çanakkale Onsekiz Mart University, Canakkale 17100, Turkey
2
Department of Computer Education and Instructional Technology, Faculty of Education, Giresun University, Giresun 28200, Turkey
*
Author to whom correspondence should be addressed.
Academic Editor: R. Alan Aitken
Molbank 2022, 2022(1), M1316; https://doi.org/10.3390/M1316
Received: 3 December 2021 / Revised: 8 January 2022 / Accepted: 10 January 2022 / Published: 14 January 2022
(This article belongs to the Section Organic Synthesis)
Herein, two title compounds, N-benzoyl-N′-(4′-cyanophenyl)thiourea (1) and N-(4-nitrobenzoyl)-N′-(4′-cyanophenyl)thiourea (2) were synthesized in a high yield, via different applications of aroyl isocyanate and 4-aminobenzonitrile. The structure of the prepared compounds was characterized by elemental analysis and FT-IR, 1H, and 13C-NMR spectroscopic methods. The crystal structure of the title compound 1 was determined by an X-ray single-crystal technique and an intramolecular C=O…H-N hydrogen bond and intermolecular C=S…H-N and C=S…H-C hydrogen interactions, which were observed for the crystal structure. The molecular electrostatic potential (MEP) and the Mulliken atomic charges of title compounds 1 and 2 were theoretically calculated and interpreted. Cyclic voltammetric (CV) experiments for the compounds were performed with the glassy carbon electrode. The reduction in potential values of the different functional groups such as nitro and cyano in title compounds were investigated using CV curves. View Full-Text
Keywords: N-aroylthioureas; CV curves; crystal structure; 4-aminobenzonitrile; MEP N-aroylthioureas; CV curves; crystal structure; 4-aminobenzonitrile; MEP
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MDPI and ACS Style

Aydin, F.; Arslan, N.B. Synthesis, Crystal Structure and Cyclic Voltammetric Behavior of N-aroyl-N′-(4′-cyanophenyl)thioureas. Molbank 2022, 2022, M1316. https://doi.org/10.3390/M1316

AMA Style

Aydin F, Arslan NB. Synthesis, Crystal Structure and Cyclic Voltammetric Behavior of N-aroyl-N′-(4′-cyanophenyl)thioureas. Molbank. 2022; 2022(1):M1316. https://doi.org/10.3390/M1316

Chicago/Turabian Style

Aydin, Fatma, and N. B. Arslan. 2022. "Synthesis, Crystal Structure and Cyclic Voltammetric Behavior of N-aroyl-N′-(4′-cyanophenyl)thioureas" Molbank 2022, no. 1: M1316. https://doi.org/10.3390/M1316

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