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Stereoselective Synthesis of a New cis Monocyclic β-lactam Bearing a Sugar Moiety at Its N1 Position and Its Physical Characterization

1
Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran
2
Department of Chemistry, University of Arizona, Tucson, AZ 85721 USA
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Author to whom correspondence should be addressed.
Molbank 2007, 2007(3), M544; https://doi.org/10.3390/M544
Received: 29 December 2006 / Accepted: 27 February 2007 / Published: 30 May 2007
Synthesis of a new monocyclic β-lactam containing a sugar moiety at its N1 position via [2+2] cycloaddition reaction of ketene and imine is described. Reaction of achiral phenoxy ketene with chiral aldimine derived from chiral 2, 3, 4, 6-tetra-O-acetyl-β-D-galactopyranosylamine and 2-hydroxy-3-methoxy benzaldehyde resulted in the formation of 2 as a single diastereomer. Then its physical characterization has been determined at the AM1 level of theory. View Full-Text
Keywords: 2-azetidinone; phenoxy ketene; asymmetric synthesis; chiral Schiff bases; sugar; [2+2] cycloaddition 2-azetidinone; phenoxy ketene; asymmetric synthesis; chiral Schiff bases; sugar; [2+2] cycloaddition
MDPI and ACS Style

Jarrahpour, A.; Jalbout, A.F.; Alvand, P. Stereoselective Synthesis of a New cis Monocyclic β-lactam Bearing a Sugar Moiety at Its N1 Position and Its Physical Characterization. Molbank 2007, 2007, M544.

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