Development of Magnetizable, Nickel–Ferrite-Decorated Carbon Nanocomposites as Hydrogenation Catalyst for Aniline Synthesis
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of the CNL and N-BCNT Nanomaterials as Catalyst Supports
2.2. Characterization of the Magnetizable, Nickel-Ferrite Decorated Carbon Nanomaterials and the Palladium Catalyst
2.3. Catalytic Tests of the Magnetic Carbon-Supported Palladium Catalysts in Nitrobenzene Hydrogenation
3. Materials and Methods
3.1. Materials
3.2. Characterization Techniques
3.3. Preparation of the Carbon Nanolayer (CNL) Sample
3.4. Preparation of the N-BCNT
3.5. Deposition of the Nickel–Ferrite Particles onto the Surfaces of the Carbon Supports
3.6. Deposition of the Palladium Nanoparticles onto the Surfaces of the Ferrite-Decorated Carbon Supports
3.7. Catalytic Tests of the Prepared Palladium Catalysts
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Sample | Atomic Percentage of Nitrogen (%) | |||
---|---|---|---|---|
Pyridinic N | Graphitic N | Pyrrolic N | Oxidized N | |
CNL | 43.6 | 15 | 32.2 | 9.2 |
N-BCNT | 31.2 | 35.7 | - | 33.1 |
wt% | NiFe2O4 | Fe3O4 | Ni | Pd |
---|---|---|---|---|
Pd/NiFe2O4-CNL | 13.9 | 0.3 | 0.3 | 3.98 |
Pd/NiFe2O4-N-BCNT | 19.6 | 5.3 | 1.0 | 4.26 |
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Prekob, Á.; Szegedi, M.P.; Muránszky, G.; Kristály, F.; Nagy, M.; Halasi, G.; Szamosvölgyi, Á.; Fiser, B.; Viskolcz, B.; Vanyorek, L. Development of Magnetizable, Nickel–Ferrite-Decorated Carbon Nanocomposites as Hydrogenation Catalyst for Aniline Synthesis. Int. J. Mol. Sci. 2023, 24, 17547. https://doi.org/10.3390/ijms242417547
Prekob Á, Szegedi MP, Muránszky G, Kristály F, Nagy M, Halasi G, Szamosvölgyi Á, Fiser B, Viskolcz B, Vanyorek L. Development of Magnetizable, Nickel–Ferrite-Decorated Carbon Nanocomposites as Hydrogenation Catalyst for Aniline Synthesis. International Journal of Molecular Sciences. 2023; 24(24):17547. https://doi.org/10.3390/ijms242417547
Chicago/Turabian StylePrekob, Ádám, Máté Péter Szegedi, Gábor Muránszky, Ferenc Kristály, Miklós Nagy, Gyula Halasi, Ákos Szamosvölgyi, Béla Fiser, Béla Viskolcz, and László Vanyorek. 2023. "Development of Magnetizable, Nickel–Ferrite-Decorated Carbon Nanocomposites as Hydrogenation Catalyst for Aniline Synthesis" International Journal of Molecular Sciences 24, no. 24: 17547. https://doi.org/10.3390/ijms242417547