Effects of the Preferential Oxidation of Phenolic Lignin Using Chlorine Dioxide on Pulp Bleaching Efficiency
Abstract
:1. Introduction
2. Results and Discussion
2.1. Oxidative Consumption of Vanillyl Alcohol and Veratryl Alcohol by Chlorine Dioxide
2.2. Differences in Oxidation Products
2.3. Analysis of Physicochemical Properties of Pulp Fibers
2.4. Structural Transformation of Lignin in Pulp
3. Materials and Methods
3.1. Materials and Reagents
3.2. Oxidation of Lignin by Chlorine Dioxide
3.3. Organic Components in the Reaction Solution
3.4. Chlorine Dioxide Oxidation of Pulp
3.5. Structural Characteristics of Lignin in Pulp
3.6. Physical and Chemical Characterization of the Pulp
4. Conclusions
Author Contributions
Funding
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Serial Number | Retention Time (min) | Relative Content | Substance Name | |
---|---|---|---|---|
Traditional Chlorine Dioxide Oxidation | Optimization Chlorine Dioxide Oxidation | |||
1 | 29.40 | 1 | 1 | 3,4-dimethoxybromobenzene |
2 | 36.39 | 0.6 | 1.0 | veratryl alcohol |
3 | 38.53 | 0.1 | 0.1 | vanillyl alcohol |
4 | 41.46 | 0.5 | 0.3 | 6-chloro-veratryl alcohol |
Samples | Brightness (%ISO) | Kappa Number | Viscosity (mPa·s) | AOX (mg·L−1) |
---|---|---|---|---|
Untreated | 29.0 | 19.2 | 1014 | / |
Traditional | 39.2 | 7.5 | 772 | 23.8 |
Optimization | 41.0 | 8.4 | 834 | 18. 0 |
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Liu, Y.; Deng, B.; Liang, J.; Li, J.; Liu, B.; Wang, F.; Qin, C.; Yao, S. Effects of the Preferential Oxidation of Phenolic Lignin Using Chlorine Dioxide on Pulp Bleaching Efficiency. Int. J. Mol. Sci. 2022, 23, 13310. https://doi.org/10.3390/ijms232113310
Liu Y, Deng B, Liang J, Li J, Liu B, Wang F, Qin C, Yao S. Effects of the Preferential Oxidation of Phenolic Lignin Using Chlorine Dioxide on Pulp Bleaching Efficiency. International Journal of Molecular Sciences. 2022; 23(21):13310. https://doi.org/10.3390/ijms232113310
Chicago/Turabian StyleLiu, Yi, Baojuan Deng, Jiarui Liang, Jiao Li, Baojie Liu, Fei Wang, Chengrong Qin, and Shuangquan Yao. 2022. "Effects of the Preferential Oxidation of Phenolic Lignin Using Chlorine Dioxide on Pulp Bleaching Efficiency" International Journal of Molecular Sciences 23, no. 21: 13310. https://doi.org/10.3390/ijms232113310