Synthesis and Characterization of a Heteroleptic Ru(II) Complex of Phenanthroline Containing Oligo-Anthracenyl Carboxylic Acid Moieties
Abstract
:1. Introduction
2. Results and Discussion
2.1. Syntheses
2.2. Infrared Spectra
2.3. NMR
2.4. Electronic and Emission Spectra
2.5. Electrochemistry
3. Experimental Section
3.1. Materials and General Physical Measurements
3.2. Synthesis of Ligand 1
3.3. Synthesis of Ligand 2
3.4. Synthesis of [Ru(II)-L1L2(NCS)2]
4. Conclusions
Supporting Information
Acknowledgements
References
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Compound | Epa/V | E1/2/V |
---|---|---|
L1 | 0.45 | −0.23, −0.59 |
L2 | 0.48 | −0.38, −0.57, 0.94 |
[RuL1L2(NCS)2] | 0.17, 0.63 | −0.27, −0.45, −0.86 |
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Adeloye, A.O.; Ajibade, P.A. Synthesis and Characterization of a Heteroleptic Ru(II) Complex of Phenanthroline Containing Oligo-Anthracenyl Carboxylic Acid Moieties. Int. J. Mol. Sci. 2010, 11, 3158-3176. https://doi.org/10.3390/ijms11093158
Adeloye AO, Ajibade PA. Synthesis and Characterization of a Heteroleptic Ru(II) Complex of Phenanthroline Containing Oligo-Anthracenyl Carboxylic Acid Moieties. International Journal of Molecular Sciences. 2010; 11(9):3158-3176. https://doi.org/10.3390/ijms11093158
Chicago/Turabian StyleAdeloye, Adewale O., and Peter A. Ajibade. 2010. "Synthesis and Characterization of a Heteroleptic Ru(II) Complex of Phenanthroline Containing Oligo-Anthracenyl Carboxylic Acid Moieties" International Journal of Molecular Sciences 11, no. 9: 3158-3176. https://doi.org/10.3390/ijms11093158