Chiral Binaphthalene Building Blocks for Self-Assembled Nanoscale CPL Emitters
Abstract
:1. Introduction
2. Results
2.1. Synthesis
2.2. Characterization of Nanostructures
2.3. Photophysical Properties
Compound | λabs (nm) | ε (104 M−1cm−1) | λem (THF, nm) | ΦTHF 2 (%) |
---|---|---|---|---|
BNPB | 307, 346 | 5.2, 4.1 | 402 | 81 |
7BBNPB | 346 | 3.7 | 432 | 72 |
8BBNPB | 335 | 5.3 | 396 | 66 |
BNBTPB | 303, 344, 403 | 7.1, 3.3, 3.6 | 549 | 28 |
7BBNBTPB | 318, 404 | 6.3, 4.1 | 538 | 42 |
BNCNCzPB | 314, 328, 403 | 5.8, 5.1, 0.56 | 525 | 21 (28) 3 |
2.4. Chiroptical Properties
3. Discussion
4. Materials and Methods
4.1. Preparation of Nanospheres
4.2. Techniques for Characterization
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Hsieh, Y.-Y.; Shyue, J.-J.; Chao, Y.-C.; Wong, K.-T.; Bassani, D.M. Chiral Binaphthalene Building Blocks for Self-Assembled Nanoscale CPL Emitters. Molecules 2023, 28, 3382. https://doi.org/10.3390/molecules28083382
Hsieh Y-Y, Shyue J-J, Chao Y-C, Wong K-T, Bassani DM. Chiral Binaphthalene Building Blocks for Self-Assembled Nanoscale CPL Emitters. Molecules. 2023; 28(8):3382. https://doi.org/10.3390/molecules28083382
Chicago/Turabian StyleHsieh, Yu-Yu, Jing-Jong Shyue, Yu-Chiang Chao, Ken-Tsung Wong, and Dario M. Bassani. 2023. "Chiral Binaphthalene Building Blocks for Self-Assembled Nanoscale CPL Emitters" Molecules 28, no. 8: 3382. https://doi.org/10.3390/molecules28083382