The Role of Polyphenolic Antioxidants from Tea and Rosemary in the Hydroxyl Radical Oxidation of N-Acetyl Alanine
Abstract
:1. Introduction
2. Results and Discussion
2.1. Hydroxyl Radical-Induced Oxidation of N-Ac-Ala-OH
2.2. Hydroxylation of Antioxidants and Quinone Formation
2.3. Hydroperoxides of Antioxidants
2.4. Antioxidant Capacity
3. Materials and Methods
3.1. Chemicals
3.2. HO•-Mediated Oxidation of N-Ac-Ala-OH in the Presence of Antioxidants
3.3. LC-MS Analysis
3.4. N-Ac-Ala-OH LC-MS Calibration Curve
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Time/min | % A | % B |
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0 | 100 | 0 |
5 | 100 | 0 |
10 | 70 | 30 |
15 | 70 | 30 |
25 | 50 | 50 |
35 | 50 | 50 |
40 | 30 | 70 |
45 | 30 | 70 |
50 | 100 | 0 |
60 | 100 | 0 |
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Vagkidis, N.; Marsh, J.; Chechik, V. The Role of Polyphenolic Antioxidants from Tea and Rosemary in the Hydroxyl Radical Oxidation of N-Acetyl Alanine. Molecules 2023, 28, 7514. https://doi.org/10.3390/molecules28227514
Vagkidis N, Marsh J, Chechik V. The Role of Polyphenolic Antioxidants from Tea and Rosemary in the Hydroxyl Radical Oxidation of N-Acetyl Alanine. Molecules. 2023; 28(22):7514. https://doi.org/10.3390/molecules28227514
Chicago/Turabian StyleVagkidis, Nikolaos, Jennifer Marsh, and Victor Chechik. 2023. "The Role of Polyphenolic Antioxidants from Tea and Rosemary in the Hydroxyl Radical Oxidation of N-Acetyl Alanine" Molecules 28, no. 22: 7514. https://doi.org/10.3390/molecules28227514