Synthesis, Structures, and Magnetism of Four One-Dimensional Complexes Using [Ni(CN)4]2− and Macrocyclic Metal Complexes
Abstract
:1. Introduction
2. Results and Discussion
2.1. Description of Structures
2.2. IR Spectra
2.3. XRD and TG
2.4. Magnetism
3. Materials and Methods
Preparation of the Compounds
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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1 | |||||
Bond | Length | Bond | Length | Bond | Length |
Ni(1)-N(1) | 2.0498(16) | Ni(1)-N(2) | 2.0712(16) | Ni(1)-N(4) | 2.1489(17) |
Ni(2)-C(6) | 1.866(2) | Ni(2)-C(7) | 1.858(2) | ||
Bond | Angle | Bond | Angle | Bond | Angle |
N(1)-Ni(1)-N(2) | 94.15(7) | N(1)-Ni(1)-N(2) #1 | 85.85(7) | N(1)-Ni(1)-N(4) #1 | 90.27(6) |
N(2)-Ni(1)-N(4) #1 | 88.33(6) | N(1)-Ni(1)-N(4) | 89.73(6) | N(2)-Ni(1)-N(4) | 91.67(6) |
N(5)-C(7)-Ni(2) | 176.0(2) | N(4)-C(6)-Ni(2) | 171.6(7) | C(6)-N(6)-Ni(1) | 149.7(5) |
2 | |||||
Bond | Length | Bond | Length | Bond | Length |
Cu(1)-N(1) | 2.0009(15) | Cu(1)-N(2) | 2.0240(16) | Cu(1)-N(5) | 2.563(2) |
Ni(1)-C(7) | 1.865(2) | Ni(1)-C(6) | 1.861(2) | ||
Bond | Angle | Bond | Angle | Bond | Angle |
N(1)-Cu(1)-N(2) | 93.72(7) | N(1)-Cu(1)-N(2) #1 | 86.28(7) | C(6)-Ni(1)-C(7) | 88.08(9) |
C(6)-Ni(1)-C(7) #2 | 91.92(9) | N(5)-C(7)-Ni(1) | 175.7(9) | N(4)-C(6)-Ni(1) | 177.3(2) |
C(7)-N(5)-Cu(1) | 127.8(8) | ||||
3 | |||||
Bond | Length | Bond | Length | Bond | Length |
Ni(1)-N(1) | 2.061(2) | Ni(1)-N(2) | 2.068(2) | Ni(1)-N(4) | 2.118(2) |
Ni(2)-C(8) | 1.864(3) | Ni(2)-C(9) | 1.862(3) | ||
Bond | Angle | Bond | Angle | Bond | Angle |
N(1)-Ni(1)-N(2) #1 | 85.66(10) | N(1)-Ni(1)-N(2) | 94.34(10) | N(1)-Ni(1)-N(4) | 92.09(10) |
N(2)-Ni(1)-N(4) | 91.21(9) | N(1)-Ni(1)-N(4) #1 | 87.91(10) | N(2)-Ni(1)-N(4) #1 | 88.79(9) |
C(9)-Ni(2)-C(8) | 91.14(11) | C(9)-Ni(2)-C(8) #3 | 88.86(11) | N(4)-C(8)-Ni(2) | 177.1(2) |
N(5)-C(9)-Ni(2) | 178.9(3) | C(8)-N(4)-Ni(1) | 148.4(2) | ||
4 | |||||
Bond | Length | Bond | Length | Bond | Length |
Cu(1)-N(1) | 2.016(2) | Cu(1)-N(2) | 2.0159(19) | Cu(1)-N(4) | 2.410(2) |
Ni(1)-C(8) | 1.864(3) | Ni(1)-C(9) | 1.865(3) | ||
Bond | Angle | Bond | Angle | Bond | Angle |
N(1)-Cu(1)-N(2) #4 | 85.93(8) | N(1)-Cu(1)-N(2) | 94.07(8) | N(1)-Cu(1)-N(4) #4 | 91.93(8) |
N(2)-Cu(1)-N(4) #4 | 91.37(9) | N(1)-Cu(1)-N(4) | 88.07(8) | N(2)-Cu(1)-N(4) | 88.63(9) |
C(8)-Ni(1)-C(9) | 90.18(11) | C(8)-Ni(1)-C(9) #5 | 89.82(11) | N(4)-C(8)-Ni(1) | 178.0(2) |
N(5)-C(9)-Ni(1) | 178.8(3) | C(8)-N(4)-Cu(1) | 160.8(2) |
Compound | [NiL1][Ni(CN)4] | [CuL1][Ni(CN)4] | [NiL2][Ni(CN)4]·2H2O | [CuL2][Ni(CN)4]·2H2O |
---|---|---|---|---|
Empirical formula | C14H26Ni2N10 | C14H26CuNiN10 | C18H38Ni2O2N10 | C18H38CuNiN10O2 |
Formula weight | 451.86 | 456.70 | 544.00 | 548.83 |
Temperature (K) | 296(2) | 296(2) | 296(2) | 296(2) |
Crystal system | Monoclinic | Monoclinic | Triclinic | Triclinic |
Space group | P2(1)/n | P2(1)/n | P-1 | P-1 |
a/Å | 9.834(3) | 9.906(4) | 8.588(8) | 8.400(4) |
b/Å | 9.167(3) | 9.110(4) | 8.873(8) | 8.771(4) |
c/Å | 10.910(4) | 10.785(5) | 10.001(9) | 10.098(4) |
α/° | 90 | 90 | 80.930(11) | 81.180(4) |
β/° | 95.177(4) | 92.268(4) | 65.954(10) | 69.590(4) |
γ/° | 90 | 90 | 67.544(10) | 67.991(4) |
V/Å3 | 979.5(6) | 972.6(7) | 643.1(10) | 646.2(5) |
Z | 4 | 2 | 2 | 1 |
Dc/Mg cm−3 | 1.532 | 1.559 | 1.405 | 1.410 |
μ/mm−1 | 1.943 | 2.082 | 1.498 | 1.585 |
F (000) | 472 | 474 | 288 | 289 |
Crystal size (mm) | 0.36 × 0.28 × 0.23 | 0.46 × 0.36 × 0.28 | 0.28 × 0.23 × 0.15 | 0.38 × 0.26 × 0.20 |
θ range | 2.67–27.46 | 2.74–27.47 | 2.23–27.44 | 2.15–27.53 |
Collected/unique | 10687/2221(0.022) | 10594/2206(0.021) | 7227/2838(0.0295) | 6873/2872(0.0306) |
Completeness to θ | 99.3% | 99.1% | 97.0% | 96.3% |
Goodness-of-fit on F2 | 1.041 | 1.012 | 0.979 | 0.991 |
Final R indices [I > 2σ (I)] | 0.0279, 0.0721 | 0.0268, 0.0716 | 0.0340, 0.0828 | 0.0356, 0.0893 |
R indices (all data) | 0.0411, 0.0799 | 0.0417, 0.0792 | 0.0554, 0.0910 | 0.0551, 0.0981 |
Max. peak/hole (e. Å−3) | 0.290/−0.173 | 0.196/−0.178 | 0.460/−0.464 | 0.605/−0.379 |
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Ou, G.; Wang, Q.; Tan, Y.; Zhou, Q. Synthesis, Structures, and Magnetism of Four One-Dimensional Complexes Using [Ni(CN)4]2− and Macrocyclic Metal Complexes. Molecules 2023, 28, 4529. https://doi.org/10.3390/molecules28114529
Ou G, Wang Q, Tan Y, Zhou Q. Synthesis, Structures, and Magnetism of Four One-Dimensional Complexes Using [Ni(CN)4]2− and Macrocyclic Metal Complexes. Molecules. 2023; 28(11):4529. https://doi.org/10.3390/molecules28114529
Chicago/Turabian StyleOu, Guangchuan, Qiong Wang, Yingzhi Tan, and Qiang Zhou. 2023. "Synthesis, Structures, and Magnetism of Four One-Dimensional Complexes Using [Ni(CN)4]2− and Macrocyclic Metal Complexes" Molecules 28, no. 11: 4529. https://doi.org/10.3390/molecules28114529