Expanded Ligands Based upon Iron(II) Coordination Compounds of Asymmetrical Bis(terpyridine) Domains
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Characterization of Terpyridine Precursors 1–4
2.2. Synthesis and Characterization of the Asymmetrical Bis(Terpyridine) Ligands 5 and 6
2.3. Expanded Ligands [Fe(5)2]2+ and [Fe(6)2]2+
3. Materials and Methods
3.1. General
3.2. Compound 1
3.3. Compound 2
3.4. Compound 3
3.5. Compound 4
3.6. Compound 5
3.7. Compound 6
3.8. [Fe(5)2][NO3]2
3.9. [Fe(6)2][BF4]2
3.10. Crystallography
3.11. Compound 2
3.12. Compound 3
3.13. Compound 4
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Rocco, D.; Prescimone, A.; Housecroft, C.E.; Constable, E.C. Expanded Ligands Based upon Iron(II) Coordination Compounds of Asymmetrical Bis(terpyridine) Domains. Molecules 2023, 28, 82. https://doi.org/10.3390/molecules28010082
Rocco D, Prescimone A, Housecroft CE, Constable EC. Expanded Ligands Based upon Iron(II) Coordination Compounds of Asymmetrical Bis(terpyridine) Domains. Molecules. 2023; 28(1):82. https://doi.org/10.3390/molecules28010082
Chicago/Turabian StyleRocco, Dalila, Alessandro Prescimone, Catherine E. Housecroft, and Edwin C. Constable. 2023. "Expanded Ligands Based upon Iron(II) Coordination Compounds of Asymmetrical Bis(terpyridine) Domains" Molecules 28, no. 1: 82. https://doi.org/10.3390/molecules28010082