Design of Deep Eutectic Systems: Plastic Crystalline Materials as Constituents
Abstract
:1. Introduction
2. Results and Discussion
2.1. Properties of Pure PCs
2.2. Eutectic Systems with PCs
2.3. Comparison with Other Eutectic Systems
3. Materials and Methods
3.1. Eutectic Systems
3.2. DSC
3.3. SLE Modeling
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Component 1 | Component 2 | Tm,2/K | ||
---|---|---|---|---|
L-menthol | Pivalic acid a,b | 308.7 | 260.6 | −48.1 |
Cyclohexane carboxylic acid [35] | 299.4 | 265.0 | −34.4 | |
Capric acid [35] | 303.9 | 279.0 | −24.9 | |
Neopentyl alcohol a,b | 328.9 | 259.2 c | −69.7 | |
Thymol [53] | 322.7 | 271.7 | −51.0 | |
Phenol [54] | 313.9 | 261.3 | −52.6 | |
Neopentyl glycol a,b | 401.2 | 291.8 | −109.4 | |
Camphor a [32] | 450.4 | 275.7 | −174.7 | |
Borneol a [32] | 480.6 | 286.7 | −193.9 | |
Sobrerol [32] | 420.2 | – d | – | |
Choline chloride a | Neopentyl glycol a,b | 401.2 | 305.1 | −96.1 |
Urea [55] | 405.2 | 297.7 | −107.5 | |
Betaine | Urea [56] | 405.2 | 359.3 | −45.9 |
Sulfamic acid | Urea [57] | 405.2 | 351.1 | −54.1 |
Compound | Ttr/K | Δhtr/kJ mol−1 | Tm/K | Δhm/kJ mol−1 | ||||
---|---|---|---|---|---|---|---|---|
This work | Literature | This work | Literature | This work | Literature | This work | Literature | |
Neopentyl alcohol | 235.9 ± 0.1 | 242.1 a | 4.46 ± 0.06 | 4.6 a | 328.9 ± 1.2 | 328.1 a | 4.01 ± 0.03 | 3.5 a |
Pivalic acid | 279.7 ± 0.1 | 278.3 b | 7.99 ± 0.32 | 8.18 b | 308.7 ± 0.2 | 309.1 b | 2.15 ± 0.13 | 2.27 b |
Neopentyl glycol | 314.7 ± 0.1 | 315.2 a | 12.86 ± 0.20 | 12.8 a | 401.2 ± 0.1 | 402.5 a | 4.16 ± 0.06 | 4.3 a |
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Alhadid, A.; Nasrallah, S.; Mokrushina, L.; Minceva, M. Design of Deep Eutectic Systems: Plastic Crystalline Materials as Constituents. Molecules 2022, 27, 6210. https://doi.org/10.3390/molecules27196210
Alhadid A, Nasrallah S, Mokrushina L, Minceva M. Design of Deep Eutectic Systems: Plastic Crystalline Materials as Constituents. Molecules. 2022; 27(19):6210. https://doi.org/10.3390/molecules27196210
Chicago/Turabian StyleAlhadid, Ahmad, Sahar Nasrallah, Liudmila Mokrushina, and Mirjana Minceva. 2022. "Design of Deep Eutectic Systems: Plastic Crystalline Materials as Constituents" Molecules 27, no. 19: 6210. https://doi.org/10.3390/molecules27196210