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Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16−

1
Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
2
Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany
3
Equipe d’Electrochimie et de Photo-électrochimie, Institut de Chimie Physique, Université Paris-Saclay, UMR 8000 CNRS, F-91405 Orsay, France
*
Author to whom correspondence should be addressed.
Molecules 2020, 25(18), 4229; https://doi.org/10.3390/molecules25184229
Received: 20 August 2020 / Revised: 8 September 2020 / Accepted: 10 September 2020 / Published: 15 September 2020
(This article belongs to the Special Issue Polyoxometalates)
Reaction of the trilacunary Wells−Dawson anion {α-P2W15O56}12− with ErIII ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H2O)(CH3COO)(P2W17O61)}2]16− (1). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of 1 were investigated. View Full-Text
Keywords: polyoxometalates; catalysis; mass spectrometry; molecular magnetism; electrochemistry; lanthanide; erbium polyoxometalates; catalysis; mass spectrometry; molecular magnetism; electrochemistry; lanthanide; erbium
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Ibrahim, M.; Baksi, A.; Peng, Y.; Al-Zeidaneen, F.K.; Mbomekallé, I.M.; de Oliveira, P.; Anson, C.E. Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16−. Molecules 2020, 25, 4229.

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