Multi-Spheres Adsorptive Microextraction (MSAμE)—Application of a Novel Analytical Approach for Monitoring Chemical Anthropogenic Markers in Environmental Water Matrices
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of the ACs
2.2. HPLC-DAD Optimization
2.3. Optimization of MSAµE(AC)-LD Assays
2.4. Validation of the MSAμE(AC(R))-LD/HPLC-DAD Method
2.5. Application to Environmental Water Matrices
3. Materials and Methods
3.1. Samples and Reagents
3.2. ACs Characterization
3.3. MSAµE Devices Preparation
3.4. Recovery Assays and Method Validation
3.5. HPLC-DAD Settings
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample Availability: Not available. |
Compounds | Microextraction Techniques | Recovery (%) | Refs. |
---|---|---|---|
CAF | MSAµE | 75.3 | This work |
SPE | 99.3 | 13 | |
SPE | 88.0 | 14 | |
SPME | 98.5 | 15 | |
ACF | MSAµE | 82.6 | This work |
SPE | 11.3 | 16 | |
SPE | 47.0 | 17 |
Compounds | Recovery (%); | |||
---|---|---|---|---|
(r2) | ||||
Ultra-Pure Water | Surface Water | Sea Water | Wastewater | |
ACF | 75.3 ± 9.5 | 64.8 ± 8.3 | 73.1 ± 2.9 | 50.1 ± 2.2 |
(0.9983) | (0.9960) | (0.9970) | (0.9953) | |
CAF | 82.6 ± 2.9 | 83.5 ± 1.1 | 74.6 ± 2.7 | 54.7 ± 5.6 |
(0.9976) | (0.9935) | (0.9975) | (0.9989) |
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Silva, A.R.M.; Neng, N.R.; Nogueira, J.M.F. Multi-Spheres Adsorptive Microextraction (MSAμE)—Application of a Novel Analytical Approach for Monitoring Chemical Anthropogenic Markers in Environmental Water Matrices. Molecules 2019, 24, 931. https://doi.org/10.3390/molecules24050931
Silva ARM, Neng NR, Nogueira JMF. Multi-Spheres Adsorptive Microextraction (MSAμE)—Application of a Novel Analytical Approach for Monitoring Chemical Anthropogenic Markers in Environmental Water Matrices. Molecules. 2019; 24(5):931. https://doi.org/10.3390/molecules24050931
Chicago/Turabian StyleSilva, Ana R. M., Nuno R. Neng, and José M. F. Nogueira. 2019. "Multi-Spheres Adsorptive Microextraction (MSAμE)—Application of a Novel Analytical Approach for Monitoring Chemical Anthropogenic Markers in Environmental Water Matrices" Molecules 24, no. 5: 931. https://doi.org/10.3390/molecules24050931