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Molecules 2019, 24(3), 420; https://doi.org/10.3390/molecules24030420

An Enantioselective Potentiometric Sensor for 2-Amino-1-Butanol Based on Chiral Porous Organic Cage CC3-R

1
Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming 650091, China
2
Department of Chemistry, Yunnan Normal University, Kunming 650500, China
*
Authors to whom correspondence should be addressed.
Received: 23 December 2018 / Revised: 19 January 2019 / Accepted: 23 January 2019 / Published: 24 January 2019
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Abstract

Porous organic cages (POCs) have attracted extensive attention due to their unique structures and tremendous application potential in numerous areas. In this study, an enantioselective potentiometric sensor composed of a polyvinyl chloride (PVC) membrane electrode modified with CC3-R POC material was used for the recognition of enantiomers of 2-amino-1-butanol. After optimisation, the developed sensor exhibited enantioselectivity toward S-2-amino-1-butanol ( log K S , R P o t = −0.98) with acceptable sensitivity, and a near-Nernstian response of 25.8 ± 0.3 mV/decade within a pH range of 6.0–9.0. View Full-Text
Keywords: enantioselective potentiometric sensor; 2-amino-1-butanol; chiral porous organic cage; CC3-R; PVC membrane electrode enantioselective potentiometric sensor; 2-amino-1-butanol; chiral porous organic cage; CC3-R; PVC membrane electrode
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Wang, B.-J.; Duan, A.-H.; Zhang, J.-H.; Xie, S.-M.; Cao, Q.-E.; Yuan, L.-M. An Enantioselective Potentiometric Sensor for 2-Amino-1-Butanol Based on Chiral Porous Organic Cage CC3-R. Molecules 2019, 24, 420.

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