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Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose

Department of Medicinal Chemistry, Pharmacy School, Jinzhou Medical University, Jinzhou 121001, Liaoning, China
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Molecules 2019, 24(20), 3678; https://doi.org/10.3390/molecules24203678
Received: 20 September 2019 / Revised: 8 October 2019 / Accepted: 11 October 2019 / Published: 12 October 2019
(This article belongs to the Section Organic Chemistry)
This is the first report of a natural ligand improving the copper-catalyzed homocouplings of (hetero)arylboronic acids. Various important synthetic biaryl intermediates in organic synthesis could be assembled via this method. To gain insight into this reaction, in situ React IR technology was used to confirm the effectivity of this catalyst system. This protocol could provide important biaryl compounds in high yields within a short time. View Full-Text
Keywords: 2-O-methyl-d-glucopyranose; copper catalyst; homocoupling; (hetero)arylboronic acids 2-O-methyl-d-glucopyranose; copper catalyst; homocoupling; (hetero)arylboronic acids
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MDPI and ACS Style

Yuan, C.; Zheng, L.; Zhao, Y. Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose. Molecules 2019, 24, 3678.

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